FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2894610488> ?p ?o ?g. }

• W2894610488 endingPage "167" @default.
• W2894610488 startingPage "160" @default.
• W2894610488 abstract "Hollow bimetallic nanostructures are perfect systems to unravel the aging mechanisms of both Pt-based alloys and highly defective nanostructures used in proton-exchange membrane fuel cell (PEMFC) cathodes, since the mobility of their surface and bulk atoms leads to detectable chemical (i.e., Ni dissolution) and physical (i.e., decrease of the density of structural defects, collapse of the nanostructure, etc.) changes. In this study, we precisely and dynamically monitored these physicochemical changes on porous hollow PtNi/C nanoparticles during an aging procedure composed of 5000 potential cycles with linear ramps between 0.6 and 1.0 or 1.1 V vs RHE by using (i) synchrotron operando wide- and small-angle X-ray scattering (WAXS and SAXS), (ii) scanning transmission electron microscopy (STEM) in combination with X-ray energy dispersive spectroscopy (X-EDS), and (iii) electrochemical measurements. The synchrotron operando WAXS and SAXS results dynamically correlated the structural changes of the hollow NPs at both the atomic (Ni depletion, lattice parameter relaxation, variation in the density of structural defects, etc.) and nanometric (restructuring of the nanoparticles/collapse of the hollow nanostructure) level. They revealed that the collapse of the hollow nanostructure was always accompanied by a significant loss of the Ni content. The 0.6–1.1 V vs RHE aging protocol resulted in a more severe depreciation of the ORR associated with a larger restructuring of the nanoparticles in comparison to the 0.6–1.0 V vs RHE aging protocol, thus providing evidence that a critical potential exists for the stability of highly defective nanoalloys." @default.
• W2894610488 created "2018-10-12" @default.
• W2894610488 creator A5000957696 @default.
• W2894610488 creator A5014725909 @default.
• W2894610488 creator A5035932055 @default.
• W2894610488 creator A5041681511 @default.
• W2894610488 creator A5041930734 @default.
• W2894610488 creator A5042114363 @default.
• W2894610488 creator A5055768065 @default.
• W2894610488 creator A5058113262 @default.
• W2894610488 creator A5071242968 @default.
• W2894610488 creator A5091793009 @default.
• W2894610488 date "2018-10-04" @default.
• W2894610488 modified "2023-10-13" @default.
• W2894610488 title "Disentangling the Degradation Pathways of Highly Defective PtNi/C Nanostructures – An Operando Wide and Small Angle X-ray Scattering Study" @default.
• W2894610488 cites W1978916568 @default.
• W2894610488 cites W1981523259 @default.
• W2894610488 cites W2006692353 @default.
• W2894610488 cites W2019247383 @default.
• W2894610488 cites W2019293153 @default.
• W2894610488 cites W2029952112 @default.
• W2894610488 cites W2037065963 @default.
• W2894610488 cites W2037720857 @default.
• W2894610488 cites W2040064643 @default.
• W2894610488 cites W2056773921 @default.
• W2894610488 cites W2070376979 @default.
• W2894610488 cites W2073872893 @default.
• W2894610488 cites W2081253323 @default.
• W2894610488 cites W2081942312 @default.
• W2894610488 cites W2083348020 @default.
• W2894610488 cites W2106664196 @default.
• W2894610488 cites W2113603381 @default.
• W2894610488 cites W2118708336 @default.
• W2894610488 cites W2154560667 @default.
• W2894610488 cites W2164008457 @default.
• W2894610488 cites W2164733830 @default.
• W2894610488 cites W2165571442 @default.
• W2894610488 cites W2213933881 @default.
• W2894610488 cites W2238674510 @default.
• W2894610488 cites W2262215104 @default.
• W2894610488 cites W2281290941 @default.
• W2894610488 cites W2316610382 @default.
• W2894610488 cites W2326587274 @default.
• W2894610488 cites W2409117302 @default.
• W2894610488 cites W2468600416 @default.
• W2894610488 cites W2551124330 @default.
• W2894610488 cites W2554421598 @default.
• W2894610488 cites W2562320754 @default.
• W2894610488 cites W2589955484 @default.
• W2894610488 cites W2592309663 @default.
• W2894610488 cites W2597917653 @default.
• W2894610488 cites W2599441113 @default.
• W2894610488 cites W2647101901 @default.
• W2894610488 cites W2668735560 @default.
• W2894610488 cites W2763900922 @default.
• W2894610488 cites W2771266071 @default.
• W2894610488 cites W3020837759 @default.
• W2894610488 doi "https://doi.org/10.1021/acscatal.8b02665" @default.
• W2894610488 hasPublicationYear "2018" @default.
• W2894610488 type Work @default.
• W2894610488 sameAs 2894610488 @default.
• W2894610488 citedByCount "19" @default.
• W2894610488 countsByYear W28946104882019 @default.
• W2894610488 countsByYear W28946104882020 @default.
• W2894610488 countsByYear W28946104882021 @default.
• W2894610488 countsByYear W28946104882022 @default.
• W2894610488 countsByYear W28946104882023 @default.
• W2894610488 crossrefType "journal-article" @default.
• W2894610488 hasAuthorship W2894610488A5000957696 @default.
• W2894610488 hasAuthorship W2894610488A5014725909 @default.
• W2894610488 hasAuthorship W2894610488A5035932055 @default.
• W2894610488 hasAuthorship W2894610488A5041681511 @default.
• W2894610488 hasAuthorship W2894610488A5041930734 @default.
• W2894610488 hasAuthorship W2894610488A5042114363 @default.
• W2894610488 hasAuthorship W2894610488A5055768065 @default.
• W2894610488 hasAuthorship W2894610488A5058113262 @default.
• W2894610488 hasAuthorship W2894610488A5071242968 @default.
• W2894610488 hasAuthorship W2894610488A5091793009 @default.
• W2894610488 hasConcept C120665830 @default.
• W2894610488 hasConcept C121332964 @default.
• W2894610488 hasConcept C127413603 @default.
• W2894610488 hasConcept C131888329 @default.
• W2894610488 hasConcept C146088050 @default.
• W2894610488 hasConcept C155672457 @default.
• W2894610488 hasConcept C161368742 @default.
• W2894610488 hasConcept C171250308 @default.
• W2894610488 hasConcept C186187911 @default.
• W2894610488 hasConcept C191486275 @default.
• W2894610488 hasConcept C192562407 @default.
• W2894610488 hasConcept C193016168 @default.
• W2894610488 hasConcept C21368211 @default.
• W2894610488 hasConcept C42360764 @default.
• W2894610488 hasConceptScore W2894610488C120665830 @default.
• W2894610488 hasConceptScore W2894610488C121332964 @default.
• W2894610488 hasConceptScore W2894610488C127413603 @default.
• W2894610488 hasConceptScore W2894610488C131888329 @default.
• W2894610488 hasConceptScore W2894610488C146088050 @default.
• W2894610488 hasConceptScore W2894610488C155672457 @default.

• next