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• W2894633427 startingPage "15460" @default.
• W2894633427 abstract "Abstract Reported is a tandem palladium‐catalyzed Heck/regioselective C(sp 3 )−H activation reaction for the divergent synthesis of spiro‐ and fused‐cyclopropanated indolines from N ‐methallylated 2‐bromoarylamides. The regioselectivity of the C−H bond activation in the σ‐alkylPd II intermediate is controlled by the solvent used. DFT calculations suggest that the polarity of solvent molecules could influence the transition‐state energy, leading to a bifurcation of the C−H bond activation in the σ‐alkylPd II intermediate." @default.
• W2894633427 created "2018-10-12" @default.
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• W2894633427 date "2018-10-24" @default.
• W2894633427 modified "2023-10-17" @default.
• W2894633427 title "Palladium‐Catalyzed Divergent Cyclopropanation by Regioselective Solvent‐Driven C(sp³)−H Bond Activation" @default.
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• W2894633427 doi "https://doi.org/10.1002/anie.201809133" @default.
• W2894633427 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30276944" @default.
• W2894633427 hasPublicationYear "2018" @default.
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