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- W2894700078 abstract "Herein we report a highly efficient and enantiospecific borylation method to synthesize a wide range of enantiopure (>99 % ee) α-amino tertiary boronic esters. The configurationally stable α-N-Boc substituted tertiary organolithium species and pinacolborane (HBpin) underwent enantiospecific borylation at -78 °C with the formation of a new stereogenic C-B bond. This reaction has a broad scope, enabling the synthesis of various α-amino tertiary boronic esters in excellent yields and, importantly, with universally excellent enantiospecificity (>99 % es) and complete retention of configuration." @default.
- W2894700078 created "2018-10-12" @default.
- W2894700078 creator A5020635247 @default.
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- W2894700078 date "2018-10-19" @default.
- W2894700078 modified "2023-10-10" @default.
- W2894700078 title "Highly Enantiospecific Borylation for Chiral α‐Amino Tertiary Boronic Esters" @default.
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- W2894700078 doi "https://doi.org/10.1002/anie.201809389" @default.
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