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• W2894711974 abstract "Abstract Photocatalytic degradation technology is an important and promising method for complete elimination of toxic organics. In this study, the photocatalytic degradation of acetochlor using α-Fe2O3 nanoparticles under H2O2/UV system was studied with UV-Vis spectrophotometer and GC MS. The degradation rate was investigated on the effects of α-Fe2O3 morphology and dosage, initial acetochlor concentration, solution pH, and H2O2 dosage. The results showed that photocatalytic degradation efficiency could reach 91% by α-Fe2O3 with 200 mg/L hollow morphology at an initial acetochlor concentration, pH value, and H2O2 dosage of 50 mg/L, 7 and 40 μL, respectively. The photocatalytic reaction mechanism and degradation process of acetochlor by α-Fe2O3 were investigated and the degradation pathway of acetochlor was proposed. The oxidative attack involves N C bond connecting the aromatic ring with side chain, the nitrogen-containing side chain, chlorinated aliphatic to produce 1-methyl-3-ving-benzene, allyl-methyl-amine and 1-chloro-2-ethoxy-ethane. These intermediate products could be further oxidized to NO3−, CO2 and H2O. These findings provide new insights for the photocatalytic degradation of organic pollutants in the using α-Fe2O3 nanoparticles to achieve pollutant degradation." @default.
• W2894711974 created "2018-10-12" @default.
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• W2894711974 date "2019-02-01" @default.
• W2894711974 modified "2023-09-26" @default.
• W2894711974 title "Photocatalytic degradation of acetochlor by α-Fe2O3 nanoparticles with different morphologies in aqueous solution system" @default.
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• W2894711974 doi "https://doi.org/10.1016/j.ijleo.2018.10.018" @default.
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