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- W2894744802 abstract "By employing reusable nanocobalt oxides as the catalysts, a site-specific oxidative C–H chalcogenation of (hetero)aryl-fused cyclic amines with various thiols and diselenides is presented for the first time. The reaction proceeds selectively at the sites of the (hetero)aryl rings para to the N atom, and enables access to a wide array of chalcogenyl N-heteroarenes. The merits of the transformation involve high step- and atom-efficiency, excellent substrate and functional compatibility, operational simplicity, and the use of a naturally abundant Co/O2 system. The present work has offered a fundamental basis for the selective synthesis of functional N-heteroarenes from readily available feedstocks." @default.
- W2894744802 created "2018-10-12" @default.
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- W2894744802 date "2018-10-04" @default.
- W2894744802 modified "2023-10-10" @default.
- W2894744802 title "Site-Specific Oxidative C–H Chalcogenation of (Hetero)Aryl-Fused Cyclic Amines Enabled by Nanocobalt Oxides" @default.
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- W2894744802 doi "https://doi.org/10.1021/acs.orglett.8b02889" @default.
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