FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2894766004> ?p ?o ?g. }

• W2894766004 endingPage "896" @default.
• W2894766004 startingPage "880" @default.
• W2894766004 abstract "Carbonyl sulfide (COS), carbon disulfide (CS2), and mercaptans (e.g., CH3SH) are unwanted sulfurous species that are produced in sulfur recovery units (SRUs). They can cause equipment corrosion, reduce catalyst activity, and are pollutants for the environment. This necessitates process optimization to minimize their formation in the SRUs using an accurate kinetic model. In this paper, new reactions of COS and mercaptans are studied using the CBS-QB3 level of theory, and their kinetics are evaluated using transition state theory. Such reactions are added to a detailed SRU reaction mechanism, and the updated mechanism is validated using the data on COS and mercaptans from lab-scale experimental setups and an industrial plant. Compared to the previous models, significant improvements in the predicted concentrations of the important species such as COS, carbon monoxide (CO), and sulfur oxides (SO and SO2) are observed due to the inclusion of the new reactions in the mechanism. The simulation studies in a homogeneous reactor within the temperature range of 800–2000 K revealed that furnace temperatures near 1300 K are required to minimize CO and COS formation, while ensuring the oxidation of methane (CH4), mercaptans, and aromatics. Mercaptan formation mainly took place at low temperatures near 900 K. Claus furnace simulations are conducted using industrial feed and operating conditions to show that the optimized inlet air temperature and fuel gas flow rate can assist in simultaneously reducing the emissions of CO and harmful sulfurous species such as COS, CH3SH, and CS2 from the furnace." @default.
• W2894766004 created "2018-10-12" @default.
• W2894766004 creator A5016902149 @default.
• W2894766004 creator A5044401909 @default.
• W2894766004 date "2018-10-04" @default.
• W2894766004 modified "2023-10-03" @default.
• W2894766004 title "A reaction kinetics study and model development to predict the formation and destruction of organosulfur species (carbonyl sulfide and mercaptans) in Claus furnace" @default.
• W2894766004 cites W123888621 @default.
• W2894766004 cites W1729210455 @default.
• W2894766004 cites W1973941827 @default.
• W2894766004 cites W1974923711 @default.
• W2894766004 cites W1976042519 @default.
• W2894766004 cites W1977544837 @default.
• W2894766004 cites W1979340657 @default.
• W2894766004 cites W1979640474 @default.
• W2894766004 cites W1983599554 @default.
• W2894766004 cites W1984554107 @default.
• W2894766004 cites W1986188016 @default.
• W2894766004 cites W1991930508 @default.
• W2894766004 cites W1992524994 @default.
• W2894766004 cites W1992620767 @default.
• W2894766004 cites W1999394545 @default.
• W2894766004 cites W2004389387 @default.
• W2894766004 cites W2011967461 @default.
• W2894766004 cites W2030722309 @default.
• W2894766004 cites W2034584994 @default.
• W2894766004 cites W2037084305 @default.
• W2894766004 cites W2077620015 @default.
• W2894766004 cites W2081226686 @default.
• W2894766004 cites W2083503627 @default.
• W2894766004 cites W2084962939 @default.
• W2894766004 cites W2086505034 @default.
• W2894766004 cites W2093443306 @default.
• W2894766004 cites W2102468142 @default.
• W2894766004 cites W2199759260 @default.
• W2894766004 cites W2216787851 @default.
• W2894766004 cites W2218777268 @default.
• W2894766004 cites W2311123140 @default.
• W2894766004 cites W2511214330 @default.
• W2894766004 cites W2614835512 @default.
• W2894766004 cites W2779339885 @default.
• W2894766004 cites W4240154878 @default.
• W2894766004 doi "https://doi.org/10.1002/kin.21226" @default.
• W2894766004 hasPublicationYear "2018" @default.
• W2894766004 type Work @default.
• W2894766004 sameAs 2894766004 @default.
• W2894766004 citedByCount "10" @default.
• W2894766004 countsByYear W28947660042019 @default.
• W2894766004 countsByYear W28947660042020 @default.
• W2894766004 countsByYear W28947660042021 @default.
• W2894766004 countsByYear W28947660042022 @default.
• W2894766004 countsByYear W28947660042023 @default.
• W2894766004 crossrefType "journal-article" @default.
• W2894766004 hasAuthorship W2894766004A5016902149 @default.
• W2894766004 hasAuthorship W2894766004A5044401909 @default.
• W2894766004 hasConcept C109209724 @default.
• W2894766004 hasConcept C121332964 @default.
• W2894766004 hasConcept C148898269 @default.
• W2894766004 hasConcept C161790260 @default.
• W2894766004 hasConcept C178790620 @default.
• W2894766004 hasConcept C179104552 @default.
• W2894766004 hasConcept C185592680 @default.
• W2894766004 hasConcept C194191183 @default.
• W2894766004 hasConcept C25366896 @default.
• W2894766004 hasConcept C2778413813 @default.
• W2894766004 hasConcept C2778798282 @default.
• W2894766004 hasConcept C2779607818 @default.
• W2894766004 hasConcept C2780564542 @default.
• W2894766004 hasConcept C2780596425 @default.
• W2894766004 hasConcept C512735826 @default.
• W2894766004 hasConcept C516920438 @default.
• W2894766004 hasConcept C518881349 @default.
• W2894766004 hasConcept C62520636 @default.
• W2894766004 hasConceptScore W2894766004C109209724 @default.
• W2894766004 hasConceptScore W2894766004C121332964 @default.
• W2894766004 hasConceptScore W2894766004C148898269 @default.
• W2894766004 hasConceptScore W2894766004C161790260 @default.
• W2894766004 hasConceptScore W2894766004C178790620 @default.
• W2894766004 hasConceptScore W2894766004C179104552 @default.
• W2894766004 hasConceptScore W2894766004C185592680 @default.
• W2894766004 hasConceptScore W2894766004C194191183 @default.
• W2894766004 hasConceptScore W2894766004C25366896 @default.
• W2894766004 hasConceptScore W2894766004C2778413813 @default.
• W2894766004 hasConceptScore W2894766004C2778798282 @default.
• W2894766004 hasConceptScore W2894766004C2779607818 @default.
• W2894766004 hasConceptScore W2894766004C2780564542 @default.
• W2894766004 hasConceptScore W2894766004C2780596425 @default.
• W2894766004 hasConceptScore W2894766004C512735826 @default.
• W2894766004 hasConceptScore W2894766004C516920438 @default.
• W2894766004 hasConceptScore W2894766004C518881349 @default.
• W2894766004 hasConceptScore W2894766004C62520636 @default.
• W2894766004 hasIssue "12" @default.
• W2894766004 hasLocation W28947660041 @default.
• W2894766004 hasOpenAccess W2894766004 @default.
• W2894766004 hasPrimaryLocation W28947660041 @default.
• W2894766004 hasRelatedWork W1965402809 @default.
• W2894766004 hasRelatedWork W1981101393 @default.
• W2894766004 hasRelatedWork W2005903699 @default.

• next