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- W2894767803 abstract "It is widely admitted that metal–organic frameworks (MOFs) are water sensitive and that high temperatures accelerate the hydrolysis phenomena and the collapse of the porous network. We have investigated here the resistance of the prototypical HKUST-1 MOF under steam flow at temperatures ranging from RT to 200 °C. Surprisingly, the porous framework is not degraded at 200 °C, whereas temperatures close to 100 °C lead to the total destruction of the MOF. This unexpected behavior is assigned to the extended interaction of water with the porous framework at temperature about 100 °C, whereas above 150 °C the transient interactions between gaseous water and the HKUST-1 framework limit the decomposition process." @default.
- W2894767803 created "2018-10-12" @default.
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- W2894767803 date "2018-10-02" @default.
- W2894767803 modified "2023-10-09" @default.
- W2894767803 title "The Surprising Stability of Cu<sub>3</sub>(btc)<sub>2</sub> Metal–Organic Framework under Steam Flow at High Temperature" @default.
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- W2894767803 doi "https://doi.org/10.1021/acs.cgd.8b00931" @default.
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