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• W2894796183 abstract "The LiMnPO4 material with Mg2+ ion substitution in transition metal site is successfully obtained by a facile solvothermal method combining with the subsequent spray drying and pyrolysis. The TEM image shows the controlled crystalline orientation of the primary Mg-doped LiMnPO4 particle, and the three-dimensional (3D) hierarchical micronano structure and the electronic structure of the Mg-doped material are investigated by the reconstructed nanotomography and X-ray absorption spectroscopy, respectively. The uniformity of Mg2+ ions substitution at the secondary particle level is confirmed by the transmission X-ray microscopy combined with X-ray absorption near edge structure. The prepared material exhibits an excellent electrochemical performance with the capacity of 156 mAh/g at the rate of 0.1 C, and good capacity retention of 100% after 400 cycles at the rate of 1 C. The in operando synchrotron X-ray diffraction data indicate that the performance improvement of the Mg-doped materials is attributed to th..." @default.
• W2894796183 created "2018-10-12" @default.
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• W2894796183 date "2018-10-01" @default.
• W2894796183 modified "2023-10-16" @default.
• W2894796183 title "Modifying High-Voltage Olivine-Type LiMnPO₄ Cathode via Mg Substitution in High-Orientation Crystal" @default.
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• W2894796183 doi "https://doi.org/10.1021/acsaem.8b00923" @default.
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