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- W2894839728 abstract "Two novel hepatocyte-targeting fluorescent probes were designed and synthesized. NPG-1 and NPG-2 show good selectivity and sensitivity toward ClO−, which were not disturbed by CO32−, HCO3−, Cl−, H2PO4−, HPO42−, OH−, NO2−, NO3−, SCN−, I−, CH3COO−, Br−, H2O2, SO42−, HS−, Na+, K+, Fe2+, TBHP, t-BuO, 1O2, HO, Cys, Hcy, GSH. The fluorescent “on-off” response of NPG-1 or NPG-2 towards ClO− could be recognized by the naked eye. The possible mechanism is that the methyl thioether group of NPG-1 or NPG-2 is oxidized to sulfoxide group by ClO−, inhibiting the intramolecular charge transfer (ICT) effect of naphthalimides. The hepatocyte-targeting capacity of the synthesized naphthalimide-based fluorescent probes follows N−OH < NP < NPG-1 < NPG-2 trend, suggesting that phosphate modification is an efficient hepatocyte-targeting strategy and co-modification with phosphate and galactose groups could synergistically improve hepatocyte-targeting effect of compounds. Our results demonstrated that the low-toxicity NPG-1 and NPG-2 probes could specifically detect hypochlorite of hepatocytes in real time." @default.
- W2894839728 created "2018-10-12" @default.
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- W2894839728 date "2019-01-01" @default.
- W2894839728 modified "2023-10-18" @default.
- W2894839728 title "Novel hepatocyte-targeting fluorescent probes for detection of hypochlorous acid: Synergistic effect of phosphate and galactose" @default.
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- W2894839728 doi "https://doi.org/10.1016/j.snb.2018.09.123" @default.
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