Matches in SemOpenAlex for { <https://semopenalex.org/work/W2894869911> ?p ?o ?g. }
- W2894869911 abstract "Abstract As one of the most efficient catalysts for the three‐component coupling reaction of aldehyde, amine, and alkyne (A 3 coupling), Au has attracted extensive attention, but there is a debating issue on whether Au δ + (δ > 0, representing the oxidation state of Au species) or Au 0 is the better active site. According to previous reports, both Au δ + and Au 0 can catalyze the A 3 coupling reaction. Therefore, the establishment of a suitable comparison model to identify the better active site is highly desired. In this work, an ideal model to identify the efficient active sites for the A 3 coupling reaction based on a metal–organic framework (MOF) platform is rationally fabricated. The Au δ + in oxidation state can be well bound to the MOF, MIL‐101‐NH 2 , via postsynthetic modification, and the Au 0 catalyst with retained MOF skeleton can be formed via a subsequent one‐step reduction, which provide ideal comparison models with the only difference in the Au oxidation state. Strikingly, the two catalysts exhibit significant activity difference in the A 3 coupling reaction. The activity of Au δ + catalyst is 11‐fold higher than that of Au 0 , which reveals that Au δ + serves as a much more effective active site in the A 3 coupling reaction." @default.
- W2894869911 created "2018-10-12" @default.
- W2894869911 creator A5014627402 @default.
- W2894869911 creator A5038041764 @default.
- W2894869911 date "2018-10-04" @default.
- W2894869911 modified "2023-10-17" @default.
- W2894869911 title "Oxidation or Reduction State of Au Stabilized by an MOF: Active Site Identification for the Three‐Component Coupling Reaction" @default.
- W2894869911 cites W1868754155 @default.
- W2894869911 cites W1964132516 @default.
- W2894869911 cites W1964312379 @default.
- W2894869911 cites W1968780456 @default.
- W2894869911 cites W1971958440 @default.
- W2894869911 cites W1988318972 @default.
- W2894869911 cites W1993357801 @default.
- W2894869911 cites W1994342755 @default.
- W2894869911 cites W1996735370 @default.
- W2894869911 cites W1999920344 @default.
- W2894869911 cites W2002799357 @default.
- W2894869911 cites W2007661885 @default.
- W2894869911 cites W2028312091 @default.
- W2894869911 cites W2041053730 @default.
- W2894869911 cites W2047551948 @default.
- W2894869911 cites W2056716101 @default.
- W2894869911 cites W2062269633 @default.
- W2894869911 cites W2074461825 @default.
- W2894869911 cites W2085213796 @default.
- W2894869911 cites W2088324835 @default.
- W2894869911 cites W2089557706 @default.
- W2894869911 cites W2100115189 @default.
- W2894869911 cites W2117994543 @default.
- W2894869911 cites W2141686621 @default.
- W2894869911 cites W2161437146 @default.
- W2894869911 cites W2162561859 @default.
- W2894869911 cites W2295840750 @default.
- W2894869911 cites W2328064830 @default.
- W2894869911 cites W2344269137 @default.
- W2894869911 cites W2491085471 @default.
- W2894869911 cites W2508338082 @default.
- W2894869911 cites W2556371294 @default.
- W2894869911 cites W2565203943 @default.
- W2894869911 cites W2565363263 @default.
- W2894869911 cites W2581591217 @default.
- W2894869911 cites W2626830377 @default.
- W2894869911 cites W2759976531 @default.
- W2894869911 cites W2769513864 @default.
- W2894869911 cites W2770529351 @default.
- W2894869911 cites W2951128301 @default.
- W2894869911 cites W4211044815 @default.
- W2894869911 cites W4255513991 @default.
- W2894869911 doi "https://doi.org/10.1002/smtd.201800216" @default.
- W2894869911 hasPublicationYear "2018" @default.
- W2894869911 type Work @default.
- W2894869911 sameAs 2894869911 @default.
- W2894869911 citedByCount "22" @default.
- W2894869911 countsByYear W28948699112019 @default.
- W2894869911 countsByYear W28948699112020 @default.
- W2894869911 countsByYear W28948699112021 @default.
- W2894869911 countsByYear W28948699112022 @default.
- W2894869911 countsByYear W28948699112023 @default.
- W2894869911 crossrefType "journal-article" @default.
- W2894869911 hasAuthorship W2894869911A5014627402 @default.
- W2894869911 hasAuthorship W2894869911A5038041764 @default.
- W2894869911 hasConcept C111472728 @default.
- W2894869911 hasConcept C131584629 @default.
- W2894869911 hasConcept C131779359 @default.
- W2894869911 hasConcept C138885662 @default.
- W2894869911 hasConcept C161790260 @default.
- W2894869911 hasConcept C178790620 @default.
- W2894869911 hasConcept C185592680 @default.
- W2894869911 hasConcept C191897082 @default.
- W2894869911 hasConcept C192562407 @default.
- W2894869911 hasConcept C21951064 @default.
- W2894869911 hasConcept C2776639384 @default.
- W2894869911 hasConcept C2778591166 @default.
- W2894869911 hasConcept C2779012754 @default.
- W2894869911 hasConcept C2779825165 @default.
- W2894869911 hasConcept C41183919 @default.
- W2894869911 hasConcept C48424934 @default.
- W2894869911 hasConcept C75473681 @default.
- W2894869911 hasConceptScore W2894869911C111472728 @default.
- W2894869911 hasConceptScore W2894869911C131584629 @default.
- W2894869911 hasConceptScore W2894869911C131779359 @default.
- W2894869911 hasConceptScore W2894869911C138885662 @default.
- W2894869911 hasConceptScore W2894869911C161790260 @default.
- W2894869911 hasConceptScore W2894869911C178790620 @default.
- W2894869911 hasConceptScore W2894869911C185592680 @default.
- W2894869911 hasConceptScore W2894869911C191897082 @default.
- W2894869911 hasConceptScore W2894869911C192562407 @default.
- W2894869911 hasConceptScore W2894869911C21951064 @default.
- W2894869911 hasConceptScore W2894869911C2776639384 @default.
- W2894869911 hasConceptScore W2894869911C2778591166 @default.
- W2894869911 hasConceptScore W2894869911C2779012754 @default.
- W2894869911 hasConceptScore W2894869911C2779825165 @default.
- W2894869911 hasConceptScore W2894869911C41183919 @default.
- W2894869911 hasConceptScore W2894869911C48424934 @default.
- W2894869911 hasConceptScore W2894869911C75473681 @default.
- W2894869911 hasFunder F4320321001 @default.
- W2894869911 hasIssue "12" @default.
- W2894869911 hasLocation W28948699111 @default.
- W2894869911 hasOpenAccess W2894869911 @default.