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• W2894879126 abstract "The quasi-reversible one-electron reduction of oxygen in dimethylsulfoxide is reported for a range of electrode materials (C, Pt, Pd, and Au) and temperatures (293–343 K). Modelling was undertaken using Butler-Volmer and symmetric Marcus-Hush methods, with the former found to provide more reproducible results for this system, in agreement with previous reports of quasi-reversible systems. The reorganisation energy for the reaction was found to be ca. 1.0 eV, and the reaction confirmed to be predominantly outer-sphere. The observed standard electrochemical rate constant (k0) is ca. 5.7 times faster for C electrodes than Pt, despite having a lower electronic density of states." @default.
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• W2894879126 date "2018-11-01" @default.
• W2894879126 modified "2023-10-14" @default.
• W2894879126 title "The electrochemical reduction kinetics of oxygen in dimethylsulfoxide" @default.
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• W2894879126 doi "https://doi.org/10.1016/j.jelechem.2018.09.052" @default.
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