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- W2894889155 abstract "Materials composed of earth abundant first-row transition metalnanoparticles supported upon zeolites serve as both fundamentally interesting and useful nanostructures. Examples such as Cu-functionalized zeolites have shown high activity for partial oxidation of methane to methanol. Currently wet impregnation serves as the most popular method for the production of these nanostructures, however the resultant metal nanoparticles are often irregular and aggregated. Here, we describe a comparably facile process for in situ formation of Cu-rich nanoparticles on the surface of commercial ZSM-5. This green, one-pot, process is carried out through simplified two-electrode electroreduction of Cu wire with minimal purification in aqueous solution. The produced materials were found to have Cu content as high as 1.60 wt. % while maintaining high surface area. High resolution transmission electron microscopy and energy dispersive X-ray spectroscopy mapping show evenly dispersed 3–5 nm Cu-rich nanoparticles on the surface of the zeolite support. These materials exhibit first order rate constants up to −5.2×10−3 s−1 for the reduction of 4-nitrophenol indicative of readily accessible catalytic sites. X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, and nitrogen physisorption are also employed to characterize the catalytic material. The robust synthesis method was applied over various times, voltages, and supports." @default.
- W2894889155 created "2018-10-12" @default.
- W2894889155 creator A5008798581 @default.
- W2894889155 creator A5022077573 @default.
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- W2894889155 date "2018-10-01" @default.
- W2894889155 modified "2023-09-27" @default.
- W2894889155 title "Electroreduction as a facile method for one-pot synthesis of CuZSM-5 nanostructures" @default.
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- W2894889155 doi "https://doi.org/10.1016/j.nanoso.2018.09.005" @default.
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