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- W2894889435 abstract "The Diels-Alder reactions of alkylhalovinylboranes have been investigated theoretically and experimentally. Alkylhalovinylboranes presented higher reactivity than the corresponding dialkylvinylboranes. Although endo/exo selectivities were high for the reactions with cyclopentadiene, facial selectivities for the chiral analogues were low. Our results demonstrate that the replacement of an alkyl group on the boron atom by a halogen increases the dienophilicity considerably." @default.
- W2894889435 created "2018-10-12" @default.
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- W2894889435 date "2018-01-01" @default.
- W2894889435 modified "2023-10-06" @default.
- W2894889435 title "Alkylhalovinylboranes: a new class of Diels–Alder dienophiles" @default.
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- W2894889435 doi "https://doi.org/10.1039/c8ra07089j" @default.
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