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- W2894896875 abstract "Several Fe(II) complexes were prepared as catalysts for the synthesis of oxazolidinones from terminal epoxides, aryl amines, and carbon dioxide. DBU (1,8-diazabicyclo[5.4.0]undec-7-ene) was identified as a highly active co-catalyst for the formation of oxazolidinones. Mechanistic studies reveal that Fe(II) complexes act as reservoirs of the two active species including Lewis acid and carbene. The epoxides were activated via a Fe-O σ-bond between the Fe atom of the Lewis acid and the oxygen atom of the epoxide. Simultaneously, a nucleophilic carbene activates CO2 to form a carbene−CO2 adduct. In addition, interactions between the Lewis acid and epoxides accelerate the reaction of epoxides with aryl amines. DBU plays a crucial role in the reaction between the β-amino alcohol and cyclic carbonate. Under mild reaction conditions, various epoxides and aryl amines were converted to the corresponding oxazolidinones with good yields in the presence of CO2." @default.
- W2894896875 created "2018-10-12" @default.
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- W2894896875 date "2018-12-01" @default.
- W2894896875 modified "2023-10-16" @default.
- W2894896875 title "Fe(II) complexes: reservoirs for Lewis acids and carbenes and their utility in the conversion of CO2 to oxazolidinones" @default.
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- W2894896875 doi "https://doi.org/10.1016/j.jcou.2018.09.025" @default.
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