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- W2894911337 abstract "Lutein, a xanthophyll carotenoid abundant in marigold flowers (Tagetes spp.), is found in the form of ester derivatives of fatty acids. Herein we present an enzymatic approach for the regioselective synthesis of 3-O-acyl monoester lutein derivatives (β-ionone selectivity, up to 17:1), using a lipase (Novozyme 435, immobilized CALB), and vinyl carboxylates (vinyl propionate and stearate) as acyl donors. The regioselectivity arises from the highly stereoselective feature of CALB. This methodology addresses the long-standing problem of regioselective monoesterification of lutein, potentially enabling novel, semisynthetic routes to other monoester xanthophyll carotenoids." @default.
- W2894911337 created "2018-10-12" @default.
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- W2894911337 date "2018-11-01" @default.
- W2894911337 modified "2023-10-18" @default.
- W2894911337 title "Highly regioselective enzymatic synthesis of lutein-3-monoesters" @default.
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- W2894911337 doi "https://doi.org/10.1016/j.tetlet.2018.10.006" @default.
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