Matches in SemOpenAlex for { <https://semopenalex.org/work/W289498327> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W289498327 abstract "In the spectrum of 4,4,6-trimethyl-2,2-diphenyl-1,3-dioxa-2-germacyclohexane, according to an analysis of the ABX spin system with additional splitting on account of methyl groups, a geminal coupling constant of 14.2 Hz and vicinal constants characteristic for axial-axial and axial-equatorial interactions of protons in the chair conformation /sup 3/J(H/sup ..lambda../H/sup ..cap alpha../) 9.7, /sup 3/J(H/sup ..lambda../H/sup e/) 2.8 Hz are observed. A chair conformation is also indicated by the reversal of the chemical shifts of the protons on the C/sup 5/ atom equatorial proton resonates in a higher field than the axial proton) (8). Also, the protons of the methyl groups on the C/sup 4/ atom give a singlet in the spectrum, which may indicate the realization of a conformation differing from the chair form or the accidental isochronism of the methyl groups. The recording of the spectrum of this compound in C/sub 6/H/sub 6/ leads to the anisochronism of the two methyl groups and the appearance of two signals." @default.
- W289498327 created "2016-06-24" @default.
- W289498327 creator A5012657901 @default.
- W289498327 creator A5022069059 @default.
- W289498327 creator A5045454585 @default.
- W289498327 date "1986-07-20" @default.
- W289498327 modified "2023-09-23" @default.
- W289498327 title "Steric structure of 4-, 4,6-, and 4,4,6-methyl-substituted 2,2-diphenyl-1,3-dioxa-2-germacyclohexane according to PMR data" @default.
- W289498327 hasPublicationYear "1986" @default.
- W289498327 type Work @default.
- W289498327 sameAs 289498327 @default.
- W289498327 citedByCount "0" @default.
- W289498327 crossrefType "journal-article" @default.
- W289498327 hasAuthorship W289498327A5012657901 @default.
- W289498327 hasAuthorship W289498327A5022069059 @default.
- W289498327 hasAuthorship W289498327A5045454585 @default.
- W289498327 hasConcept C109214941 @default.
- W289498327 hasConcept C121332964 @default.
- W289498327 hasConcept C145148216 @default.
- W289498327 hasConcept C178790620 @default.
- W289498327 hasConcept C181500209 @default.
- W289498327 hasConcept C183276030 @default.
- W289498327 hasConcept C184779094 @default.
- W289498327 hasConcept C185592680 @default.
- W289498327 hasConcept C201194858 @default.
- W289498327 hasConcept C2778565081 @default.
- W289498327 hasConcept C2779758233 @default.
- W289498327 hasConcept C2781311116 @default.
- W289498327 hasConcept C30095370 @default.
- W289498327 hasConcept C33062035 @default.
- W289498327 hasConcept C54516573 @default.
- W289498327 hasConcept C62520636 @default.
- W289498327 hasConcept C71240020 @default.
- W289498327 hasConcept C8010536 @default.
- W289498327 hasConceptScore W289498327C109214941 @default.
- W289498327 hasConceptScore W289498327C121332964 @default.
- W289498327 hasConceptScore W289498327C145148216 @default.
- W289498327 hasConceptScore W289498327C178790620 @default.
- W289498327 hasConceptScore W289498327C181500209 @default.
- W289498327 hasConceptScore W289498327C183276030 @default.
- W289498327 hasConceptScore W289498327C184779094 @default.
- W289498327 hasConceptScore W289498327C185592680 @default.
- W289498327 hasConceptScore W289498327C201194858 @default.
- W289498327 hasConceptScore W289498327C2778565081 @default.
- W289498327 hasConceptScore W289498327C2779758233 @default.
- W289498327 hasConceptScore W289498327C2781311116 @default.
- W289498327 hasConceptScore W289498327C30095370 @default.
- W289498327 hasConceptScore W289498327C33062035 @default.
- W289498327 hasConceptScore W289498327C54516573 @default.
- W289498327 hasConceptScore W289498327C62520636 @default.
- W289498327 hasConceptScore W289498327C71240020 @default.
- W289498327 hasConceptScore W289498327C8010536 @default.
- W289498327 hasLocation W2894983271 @default.
- W289498327 hasOpenAccess W289498327 @default.
- W289498327 hasPrimaryLocation W2894983271 @default.
- W289498327 hasRelatedWork W1587109774 @default.
- W289498327 hasRelatedWork W1657418355 @default.
- W289498327 hasRelatedWork W1948703750 @default.
- W289498327 hasRelatedWork W1978433057 @default.
- W289498327 hasRelatedWork W1978655838 @default.
- W289498327 hasRelatedWork W1980969566 @default.
- W289498327 hasRelatedWork W1988974415 @default.
- W289498327 hasRelatedWork W1990604595 @default.
- W289498327 hasRelatedWork W2015545204 @default.
- W289498327 hasRelatedWork W2040247939 @default.
- W289498327 hasRelatedWork W2048690207 @default.
- W289498327 hasRelatedWork W2053442295 @default.
- W289498327 hasRelatedWork W2068113214 @default.
- W289498327 hasRelatedWork W2083640525 @default.
- W289498327 hasRelatedWork W2088188347 @default.
- W289498327 hasRelatedWork W2210904171 @default.
- W289498327 hasRelatedWork W2322595453 @default.
- W289498327 hasRelatedWork W2343068524 @default.
- W289498327 hasRelatedWork W2376933347 @default.
- W289498327 hasRelatedWork W3036320981 @default.
- W289498327 isParatext "false" @default.
- W289498327 isRetracted "false" @default.
- W289498327 magId "289498327" @default.
- W289498327 workType "article" @default.