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- W2895045304 abstract "Abstract New hemi‐cage compounds with the formula Pd 2 ( L1 ) 2 ( L2 ) 2 ( L1 =ditopic pyridine ligand, L2 =bpy or TMEDA) have been synthesized and characterized by spectroscopic methods, X‐ray crystallography and electronic structure methods. The host‐guest chemistry of these new structures, with naphthoquinone as a guest, reveals the key role of the host shape and flexibility on competitive binding processes. The influence of counteranions, solvent and non‐covalent interactions to binding were quantified by Density Functional Theory calculations. Together, this study provides new insights into the concept of pre‐organized guest binding when applied to charged, coordination‐assembled hosts." @default.
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- W2895045304 date "2018-10-05" @default.
- W2895045304 modified "2023-10-16" @default.
- W2895045304 title "Host‐Guest Chemistry of Self‐Assembled Hemi‐Cage Systems: The Dramatic Effect of Lost Pre‐Organization" @default.
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- W2895045304 doi "https://doi.org/10.1002/ijch.201800106" @default.
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