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- W2895085170 abstract "A series of square-planar, low-spin Co(II) and Co(III) complexes supported by the POCOP pincer ligand have been prepared for the purpose of exploring the reactions potentially involved in aryl halide coupling catalysis (POCOP = 2,6-diisopropylphosphinoxyphenyl). The investigations determined that the Co(III)–aryl intermediates of the envisioned catalytic cycle are accessible, but the desired catalysis is derailed by a C–C reductive elimination reaction that involves the POCOP ligand. Metalation of the parent (POCOP)H ligand with CoCl2 and DMAP led to the formation of (POCOP)CoCl (A-1). Metathesis of A-1 with Me3SiX reagents allowed isolation of (POCOP)CoBr (A-2), (POCOP)CoI (A-3), and (POCOP)CoOTf (A-4). Reactions of A-1 with NaOtBu, MeLi, and PhLi led to (POCOP)CoOtBu (A-5), (POCOP)CoMe (A-6), and (POCOP)CoPh (A-7). Treatment of A-1 with PhSH surprisingly led to (POCOP)CoSPh (A-8) without the need for added base. A-7 could be oxidized to (POCOP)Co(Ph)(Cl) (B-1) using N-chlorosuccinimide; however, samples..." @default.
- W2895085170 created "2018-10-12" @default.
- W2895085170 creator A5029906433 @default.
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- W2895085170 date "2018-10-05" @default.
- W2895085170 modified "2023-10-12" @default.
- W2895085170 title "Synthesis of (POCOP)Co(Ph)(X) Pincer Complexes and Observation of Aryl–Aryl Reductive Elimination Involving the Pincer Aryl" @default.
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- W2895085170 doi "https://doi.org/10.1021/acs.organomet.8b00511" @default.
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