FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2895097813> ?p ?o ?g. }

• W2895097813 endingPage "6748" @default.
• W2895097813 startingPage "6737" @default.
• W2895097813 abstract "Abstract Oxidation of a 15-methylenebicyclo[9.3.1]pentadeca-3,7-dien-14-ol with a 10-phenylsulfonyl substituent provided a 14-oxobicyclo[9.3.1]pentadeca-1(15),3,7-triene-15-carbaldehyde that on reduction with DIBAL-H was converted into a 15-hydroxymethylbicyclo[9.3.1]pentadeca-1(15),3,7-triene-14-ol with the relative configuration at C14 required for incorporation into a synthesis of phomactin A. The oxidation and reduction of an analogous 3,4-epoxide that lacked the 10-phenylsulfonyl group gave a diol with the opposite relative configuration at C14. However, the TPAP oxidation and DIBAL-H reduction of a 14-hydroxy-15-methylene-3,4-epoxide that still had the 10-phenylsulfonyl group gave a diol with the required configuration at C14 although the expected spontaneous participation of the 14-hydroxyl group in an intramolecular epoxide ring-opening was only observed under Lewis acidic conditions." @default.
• W2895097813 created "2018-10-12" @default.
• W2895097813 creator A5026093824 @default.
• W2895097813 creator A5035899527 @default.
• W2895097813 creator A5040762176 @default.
• W2895097813 creator A5090340354 @default.
• W2895097813 date "2018-11-01" @default.
• W2895097813 modified "2023-09-24" @default.
• W2895097813 title "Synthetic approaches to phomactins: Late stage stereochemical and reactivity issues" @default.
• W2895097813 cites W1965847972 @default.
• W2895097813 cites W1966956544 @default.
• W2895097813 cites W1972730086 @default.
• W2895097813 cites W1975208637 @default.
• W2895097813 cites W1980288590 @default.
• W2895097813 cites W1985733060 @default.
• W2895097813 cites W1995041344 @default.
• W2895097813 cites W1997279474 @default.
• W2895097813 cites W1997815824 @default.
• W2895097813 cites W1998996936 @default.
• W2895097813 cites W2004396563 @default.
• W2895097813 cites W2008233131 @default.
• W2895097813 cites W2022716149 @default.
• W2895097813 cites W2030103668 @default.
• W2895097813 cites W2033123155 @default.
• W2895097813 cites W2048455889 @default.
• W2895097813 cites W2052661902 @default.
• W2895097813 cites W2077758783 @default.
• W2895097813 cites W2112778536 @default.
• W2895097813 cites W2129595628 @default.
• W2895097813 cites W2134431433 @default.
• W2895097813 cites W2135437997 @default.
• W2895097813 cites W2138204719 @default.
• W2895097813 cites W2165381551 @default.
• W2895097813 cites W2175429692 @default.
• W2895097813 cites W2327534096 @default.
• W2895097813 cites W2327568195 @default.
• W2895097813 cites W2327895045 @default.
• W2895097813 cites W2554547173 @default.
• W2895097813 cites W2804045355 @default.
• W2895097813 cites W2950190480 @default.
• W2895097813 cites W2952228643 @default.
• W2895097813 cites W2952639280 @default.
• W2895097813 cites W2953112818 @default.
• W2895097813 cites W2953134102 @default.
• W2895097813 doi "https://doi.org/10.1016/j.tet.2018.10.004" @default.
• W2895097813 hasPublicationYear "2018" @default.
• W2895097813 type Work @default.
• W2895097813 sameAs 2895097813 @default.
• W2895097813 citedByCount "1" @default.
• W2895097813 countsByYear W28950978132020 @default.
• W2895097813 crossrefType "journal-article" @default.
• W2895097813 hasAuthorship W2895097813A5026093824 @default.
• W2895097813 hasAuthorship W2895097813A5035899527 @default.
• W2895097813 hasAuthorship W2895097813A5040762176 @default.
• W2895097813 hasAuthorship W2895097813A5090340354 @default.
• W2895097813 hasBestOaLocation W28950978132 @default.
• W2895097813 hasConcept C142724271 @default.
• W2895097813 hasConcept C147789679 @default.
• W2895097813 hasConcept C155647269 @default.
• W2895097813 hasConcept C161790260 @default.
• W2895097813 hasConcept C172456720 @default.
• W2895097813 hasConcept C17525397 @default.
• W2895097813 hasConcept C178790620 @default.
• W2895097813 hasConcept C185592680 @default.
• W2895097813 hasConcept C204787440 @default.
• W2895097813 hasConcept C2776910235 @default.
• W2895097813 hasConcept C2776920199 @default.
• W2895097813 hasConcept C2777454769 @default.
• W2895097813 hasConcept C2778689049 @default.
• W2895097813 hasConcept C2779515768 @default.
• W2895097813 hasConcept C2780378348 @default.
• W2895097813 hasConcept C2986853022 @default.
• W2895097813 hasConcept C52859227 @default.
• W2895097813 hasConcept C71240020 @default.
• W2895097813 hasConcept C71924100 @default.
• W2895097813 hasConcept C75079739 @default.
• W2895097813 hasConceptScore W2895097813C142724271 @default.
• W2895097813 hasConceptScore W2895097813C147789679 @default.
• W2895097813 hasConceptScore W2895097813C155647269 @default.
• W2895097813 hasConceptScore W2895097813C161790260 @default.
• W2895097813 hasConceptScore W2895097813C172456720 @default.
• W2895097813 hasConceptScore W2895097813C17525397 @default.
• W2895097813 hasConceptScore W2895097813C178790620 @default.
• W2895097813 hasConceptScore W2895097813C185592680 @default.
• W2895097813 hasConceptScore W2895097813C204787440 @default.
• W2895097813 hasConceptScore W2895097813C2776910235 @default.
• W2895097813 hasConceptScore W2895097813C2776920199 @default.
• W2895097813 hasConceptScore W2895097813C2777454769 @default.
• W2895097813 hasConceptScore W2895097813C2778689049 @default.
• W2895097813 hasConceptScore W2895097813C2779515768 @default.
• W2895097813 hasConceptScore W2895097813C2780378348 @default.
• W2895097813 hasConceptScore W2895097813C2986853022 @default.
• W2895097813 hasConceptScore W2895097813C52859227 @default.
• W2895097813 hasConceptScore W2895097813C71240020 @default.
• W2895097813 hasConceptScore W2895097813C71924100 @default.
• W2895097813 hasConceptScore W2895097813C75079739 @default.
• W2895097813 hasIssue "47" @default.
• W2895097813 hasLocation W28950978131 @default.

• next