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- W2895277239 abstract "The reduction behavior of Fe3+ during the preparation of a zero-valent iron cocoanut biochar (ZBC8-3) by the carbothermic reduction method was analyzed. Fe3+ was first converted into Fe3O4, which was subsequently decomposed into FeO, and finally reduced to Fe0. A minor amount of γ-Fe2O3 was produced in the process. The isothermal thermodynamic data for the removal of Cu(ii) over ZBC8-3 followed a Langmuir model. The Langmuir equation revealed a maximum removal capacity of 169.49 mg g-1 at pH = 5 for ZBC8-3. The removal of Cu(ii) over ZBC8-3 fitted well to a pseudo-first-order equation, which suggested that the rate limiting step of the process was diffusion. The Cu(ii) removal mechanism on ZBC8-3 involved the reduction of Cu(ii) by Fe0 to produce Cu0 and Cu2O, while C[double bond, length as m-dash]C, C-O-, and -O-H formed a complex with Cu(ii)." @default.
- W2895277239 created "2018-10-12" @default.
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- W2895277239 date "2018-01-01" @default.
- W2895277239 modified "2023-10-16" @default.
- W2895277239 title "Pyrolytic behavior of a zero-valent iron biochar composite and its Cu(<scp>ii</scp>) removal mechanism" @default.
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- W2895277239 doi "https://doi.org/10.1039/c8ra05676e" @default.
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