FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2895280353> ?p ?o ?g. }

• W2895280353 endingPage "8685" @default.
• W2895280353 startingPage "8674" @default.
• W2895280353 abstract "Ethylene oxidation initiated by ozone addition (ozonolysis) is carried out in a jet-stirred reactor from 300 to 1000 K to explore the kinetic pathways relevant to low-temperature oxidation. The temperature dependencies of species’ mole fractions are quantified using molecular-beam mass spectrometry with electron ionization and single-photon ionization employing tunable synchrotron-generated vacuum-ultraviolet radiation. Upon ozone addition, significant ethylene oxidation is found in the low-temperature regime from 300 to 600 K. Here, we provide new insights into the ethylene ozonolysis reaction network via identification and quantification of previously elusive intermediates by combining experimental photoionization energy scans and ab initio threshold energy calculations for isomer identification. Specifically, the C2H4 + O3 adduct C2H4O3 is identified as a keto-hydroperoxide (hydroperoxy-acetaldehyde, HOOCH2CHO) based on the calculated and experimentally observed ionization energy of 9.80 (±0.05) eV. Quantification using a photoionization cross-section of 5 Mb at 10.5 eV results in 5 ppm at atmospheric conditions, which decreases monotonically with temperature until 550 K. Other hydroperoxide species that contribute in larger amounts to the low-temperature oxidation of C2H4, like H2O2, CH3OOH, and C2H5OOH, are identified and their temperature-dependent mole fractions are reported. The experimental evidence for additional oxygenated species such as methanol, ketene, acetaldehyde, and hydroxy-acetaldehyde suggest multiple active oxidation routes. This experimental investigation closes the gap between ozonolysis at atmospheric and elevated temperature conditions and provides a database for future modeling." @default.
• W2895280353 created "2018-10-12" @default.
• W2895280353 creator A5024017867 @default.
• W2895280353 creator A5048722132 @default.
• W2895280353 creator A5064877543 @default.
• W2895280353 creator A5081250081 @default.
• W2895280353 date "2018-10-07" @default.
• W2895280353 modified "2023-10-12" @default.
• W2895280353 title "Low-Temperature Oxidation of Ethylene by Ozone in a Jet-Stirred Reactor" @default.
• W2895280353 cites W1204093546 @default.
• W2895280353 cites W1671161451 @default.
• W2895280353 cites W1921935873 @default.
• W2895280353 cites W1940976167 @default.
• W2895280353 cites W1966739003 @default.
• W2895280353 cites W1968313783 @default.
• W2895280353 cites W1969096829 @default.
• W2895280353 cites W1974243343 @default.
• W2895280353 cites W1976272481 @default.
• W2895280353 cites W1977299829 @default.
• W2895280353 cites W1982946379 @default.
• W2895280353 cites W1984746227 @default.
• W2895280353 cites W1985494958 @default.
• W2895280353 cites W1997590333 @default.
• W2895280353 cites W1999766112 @default.
• W2895280353 cites W1999847768 @default.
• W2895280353 cites W2000137064 @default.
• W2895280353 cites W2000506423 @default.
• W2895280353 cites W2003012870 @default.
• W2895280353 cites W2004219383 @default.
• W2895280353 cites W2005655883 @default.
• W2895280353 cites W2009256533 @default.
• W2895280353 cites W2024142036 @default.
• W2895280353 cites W2027086155 @default.
• W2895280353 cites W2036812881 @default.
• W2895280353 cites W2041452168 @default.
• W2895280353 cites W2041615985 @default.
• W2895280353 cites W2044279110 @default.
• W2895280353 cites W2045325712 @default.
• W2895280353 cites W2048402930 @default.
• W2895280353 cites W2058569695 @default.
• W2895280353 cites W2058577562 @default.
• W2895280353 cites W2060954871 @default.
• W2895280353 cites W2071504828 @default.
• W2895280353 cites W2082021447 @default.
• W2895280353 cites W2082443185 @default.
• W2895280353 cites W2083412571 @default.
• W2895280353 cites W2095990435 @default.
• W2895280353 cites W2120642731 @default.
• W2895280353 cites W2126841669 @default.
• W2895280353 cites W2132270412 @default.
• W2895280353 cites W2144463216 @default.
• W2895280353 cites W2151032656 @default.
• W2895280353 cites W2152186067 @default.
• W2895280353 cites W2160178264 @default.
• W2895280353 cites W2171504088 @default.
• W2895280353 cites W2171567418 @default.
• W2895280353 cites W2204624080 @default.
• W2895280353 cites W2211790372 @default.
• W2895280353 cites W2320142414 @default.
• W2895280353 cites W2320712911 @default.
• W2895280353 cites W2330646209 @default.
• W2895280353 cites W2437421313 @default.
• W2895280353 cites W2461571601 @default.
• W2895280353 cites W2501488985 @default.
• W2895280353 cites W2518843691 @default.
• W2895280353 cites W2519456826 @default.
• W2895280353 cites W2523645431 @default.
• W2895280353 cites W2562276129 @default.
• W2895280353 cites W2610761560 @default.
• W2895280353 cites W2623683509 @default.
• W2895280353 cites W2760203907 @default.
• W2895280353 cites W2800555895 @default.
• W2895280353 cites W2877021292 @default.
• W2895280353 cites W566996405 @default.
• W2895280353 doi "https://doi.org/10.1021/acs.jpca.8b06556" @default.
• W2895280353 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30293425" @default.
• W2895280353 hasPublicationYear "2018" @default.
• W2895280353 type Work @default.
• W2895280353 sameAs 2895280353 @default.
• W2895280353 citedByCount "54" @default.
• W2895280353 countsByYear W28952803532018 @default.
• W2895280353 countsByYear W28952803532019 @default.
• W2895280353 countsByYear W28952803532020 @default.
• W2895280353 countsByYear W28952803532021 @default.
• W2895280353 countsByYear W28952803532022 @default.
• W2895280353 countsByYear W28952803532023 @default.
• W2895280353 crossrefType "journal-article" @default.
• W2895280353 hasAuthorship W2895280353A5024017867 @default.
• W2895280353 hasAuthorship W2895280353A5048722132 @default.
• W2895280353 hasAuthorship W2895280353A5064877543 @default.
• W2895280353 hasAuthorship W2895280353A5081250081 @default.
• W2895280353 hasBestOaLocation W28952803532 @default.
• W2895280353 hasConcept C113196181 @default.
• W2895280353 hasConcept C145148216 @default.
• W2895280353 hasConcept C158749347 @default.
• W2895280353 hasConcept C161790260 @default.
• W2895280353 hasConcept C178790620 @default.
• W2895280353 hasConcept C185592680 @default.

• next