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- W2895541398 abstract "Here, we report a simple and useful strategy for a series of C3-symmetric π-conjugated and highly soluble spiro-annulated truxene derivatives. The role of substituent at C5, C10, C15, C2, C7, and C12 positions was studied. We observed that truxenes containing carbonyl groups showed red shift in the absorption maxima in comparison with compounds devoid of carbonyl group. Enhanced conjugation in these systems may be responsible for this red shift. It was observed that truxene derivatives with carbonyl moiety exhibited faster decay than other derivatives. Benzyl groups play some role in the excited state dynamics as decay becomes slower when the spiro moiety was replaced by benzyl group at C5, C10, and C15 positions. Additionally, we noticed the highest quantum yield in t-butanol solvent and least in acetonitrile." @default.
- W2895541398 created "2018-10-12" @default.
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- W2895541398 date "2018-11-01" @default.
- W2895541398 modified "2023-09-25" @default.
- W2895541398 title "Synthesis and photophysical properties of star-shaped blue green emitting π-conjugated spirotruxenes" @default.
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- W2895541398 doi "https://doi.org/10.1016/j.tetlet.2018.10.005" @default.
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