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- W2895549049 abstract "An iridium-catalyzed highly efficient asymmetric hydrogenation of challenging tetrasubstituted α-fluoro-β-enamino esters was successfully developed using bisphosphine-thiourea (ZhaoPhos) as the ligand, which prepared a series of chiral α-fluoro-β-amino esters containing two adjacent tertiary stereocenters with high yields and excellent diastereoselectivities/enantioselectivities (73%-99% yields, >25:1 dr, 91%->99% ee, and turnover number (TON) values up to 8600), and no defluorinate byproduct was detected." @default.
- W2895549049 created "2018-10-12" @default.
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- W2895549049 date "2018-10-02" @default.
- W2895549049 modified "2023-10-15" @default.
- W2895549049 title "Iridium-Catalyzed Asymmetric Hydrogenation of Tetrasubstituted α-Fluoro-β-enamino Esters: Efficient Access to Chiral α-Fluoro-β-amino Esters with Two Adjacent Tertiary Stereocenters" @default.
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- W2895549049 doi "https://doi.org/10.1021/acs.orglett.8b02503" @default.
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