FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2895559250> ?p ?o ?g. }

• W2895559250 endingPage "5532" @default.
• W2895559250 startingPage "5523" @default.
• W2895559250 abstract "Abstract The complex microkinetics of the selective oxidation of n ‐butane to maleic anhydride (MAN) over vanadyl pyrophosphate‐based (VPP) catalysts has been widely investigated so far, however, they are still under debate. We present novel results of kinetic analyses and isotope labeling to shed light on the activation of gas‐phase oxygen and the dynamics of oxygen species on the catalyst surface and in the bulk. We suggest the existence of at least two catalytically relevant surface oxygen species responsible for selective and unselective activation of n ‐butane, which are formed by adsorption and consecutive dissociation of O 2 at the active site. The formation of selective [O] from unselective [O 2 ] is likely promoted by co‐fed H 2 O, which increases the MAN selectivity. Regarding the VPP bulk serving as a reservoir for active [O] species it is concluded that the dynamic exchange is limited to the amorphous surface layer forming under reaction conditions, whereas the crystalline bulk is not involved into the reaction. Labelling studies are heavily influenced by vital 16 O/ 18 O scrambling of MAN isotopes with the reaction product H 2 O." @default.
• W2895559250 created "2018-10-12" @default.
• W2895559250 creator A5007108503 @default.
• W2895559250 creator A5046221386 @default.
• W2895559250 creator A5057768225 @default.
• W2895559250 creator A5061251166 @default.
• W2895559250 date "2018-11-09" @default.
• W2895559250 modified "2023-10-13" @default.
• W2895559250 title "Selective Oxidation of <i>n</i>‐Butane over Vanadium‐Phosphorus Oxide: Oxygen Activation and Dynamics" @default.
• W2895559250 cites W1484333193 @default.
• W2895559250 cites W155654040 @default.
• W2895559250 cites W1593785150 @default.
• W2895559250 cites W1981353018 @default.
• W2895559250 cites W1987206142 @default.
• W2895559250 cites W1987919922 @default.
• W2895559250 cites W1989224072 @default.
• W2895559250 cites W1996858512 @default.
• W2895559250 cites W2000357901 @default.
• W2895559250 cites W2012253823 @default.
• W2895559250 cites W2025872332 @default.
• W2895559250 cites W2026301692 @default.
• W2895559250 cites W2029096347 @default.
• W2895559250 cites W2030371903 @default.
• W2895559250 cites W2032409000 @default.
• W2895559250 cites W2037912982 @default.
• W2895559250 cites W2047906705 @default.
• W2895559250 cites W2056595641 @default.
• W2895559250 cites W2057883002 @default.
• W2895559250 cites W2059594545 @default.
• W2895559250 cites W2060498289 @default.
• W2895559250 cites W2060606530 @default.
• W2895559250 cites W2080173673 @default.
• W2895559250 cites W2102609174 @default.
• W2895559250 cites W2123380076 @default.
• W2895559250 cites W2167098168 @default.
• W2895559250 cites W2324443996 @default.
• W2895559250 cites W2496933785 @default.
• W2895559250 cites W2513756833 @default.
• W2895559250 cites W2564870358 @default.
• W2895559250 cites W2756416236 @default.
• W2895559250 cites W2890433360 @default.
• W2895559250 cites W2951846543 @default.
• W2895559250 cites W3021473676 @default.
• W2895559250 doi "https://doi.org/10.1002/cctc.201801177" @default.
• W2895559250 hasPublicationYear "2018" @default.
• W2895559250 type Work @default.
• W2895559250 sameAs 2895559250 @default.
• W2895559250 citedByCount "11" @default.
• W2895559250 countsByYear W28955592502019 @default.
• W2895559250 countsByYear W28955592502020 @default.
• W2895559250 countsByYear W28955592502022 @default.
• W2895559250 countsByYear W28955592502023 @default.
• W2895559250 crossrefType "journal-article" @default.
• W2895559250 hasAuthorship W2895559250A5007108503 @default.
• W2895559250 hasAuthorship W2895559250A5046221386 @default.
• W2895559250 hasAuthorship W2895559250A5057768225 @default.
• W2895559250 hasAuthorship W2895559250A5061251166 @default.
• W2895559250 hasConcept C102931765 @default.
• W2895559250 hasConcept C118792377 @default.
• W2895559250 hasConcept C147789679 @default.
• W2895559250 hasConcept C150394285 @default.
• W2895559250 hasConcept C15920480 @default.
• W2895559250 hasConcept C161790260 @default.
• W2895559250 hasConcept C178790620 @default.
• W2895559250 hasConcept C179104552 @default.
• W2895559250 hasConcept C181199279 @default.
• W2895559250 hasConcept C185592680 @default.
• W2895559250 hasConcept C2776043855 @default.
• W2895559250 hasConcept C2777666793 @default.
• W2895559250 hasConcept C2778717364 @default.
• W2895559250 hasConcept C2781327020 @default.
• W2895559250 hasConcept C504678139 @default.
• W2895559250 hasConcept C521977710 @default.
• W2895559250 hasConcept C540031477 @default.
• W2895559250 hasConcept C75473681 @default.
• W2895559250 hasConceptScore W2895559250C102931765 @default.
• W2895559250 hasConceptScore W2895559250C118792377 @default.
• W2895559250 hasConceptScore W2895559250C147789679 @default.
• W2895559250 hasConceptScore W2895559250C150394285 @default.
• W2895559250 hasConceptScore W2895559250C15920480 @default.
• W2895559250 hasConceptScore W2895559250C161790260 @default.
• W2895559250 hasConceptScore W2895559250C178790620 @default.
• W2895559250 hasConceptScore W2895559250C179104552 @default.
• W2895559250 hasConceptScore W2895559250C181199279 @default.
• W2895559250 hasConceptScore W2895559250C185592680 @default.
• W2895559250 hasConceptScore W2895559250C2776043855 @default.
• W2895559250 hasConceptScore W2895559250C2777666793 @default.
• W2895559250 hasConceptScore W2895559250C2778717364 @default.
• W2895559250 hasConceptScore W2895559250C2781327020 @default.
• W2895559250 hasConceptScore W2895559250C504678139 @default.
• W2895559250 hasConceptScore W2895559250C521977710 @default.
• W2895559250 hasConceptScore W2895559250C540031477 @default.
• W2895559250 hasConceptScore W2895559250C75473681 @default.
• W2895559250 hasIssue "23" @default.
• W2895559250 hasLocation W28955592501 @default.
• W2895559250 hasOpenAccess W2895559250 @default.
• W2895559250 hasPrimaryLocation W28955592501 @default.
• W2895559250 hasRelatedWork W118557474 @default.

• next