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• W2895564966 abstract "Amines in heteroaromatic systems and pharmaceutical intermediates were functionalized through N-methylation with methanol using a palladium-loaded titanium dioxide (Pd/TiO2) photocatalyst. This method provides access to a series of tertiary N-methylamines bearing N-, O-, and/or S-containing heteroaromatic functionalities from primary/secondary amines and methanol under mild reaction conditions. Facile syntheses of several pharmaceuticals containing N-methyl or ethyl groups, as well as related deuterated drugs, was achieved through the late-stage functionalization of amines." @default.
• W2895564966 created "2018-10-12" @default.
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• W2895564966 date "2018-10-03" @default.
• W2895564966 modified "2023-09-24" @default.
• W2895564966 title "Photocatalytic N-Methylation of Amines over Pd/TiO₂ for the Functionalization of Heterocycles and Pharmaceutical Intermediates" @default.
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• W2895564966 doi "https://doi.org/10.1021/acssuschemeng.8b03855" @default.
• W2895564966 hasPublicationYear "2018" @default.
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