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• W2895585370 abstract "This study investigated the significant influence of HCO3– on the degradation of contaminants of emerging concern (CECs) during nitrate photolysis at 254 nm for water reuse applications. The second-order rate constants for the reactions between selected contaminants with carbonate radical (CO3•–) were determined at pH 8.8 and T = 20 °C: estrone ((5.3 ± 1.1) × 108 M–1 s–1), bisphenol A ((2.8 ± 0.2) × 108 M–1 s–1), 17α-ethynylestradiol ((1.6 ± 0.3) × 108 M–1 s–1), triclosan ((4.2 ± 1.4) × 107 M–1 s–1), diclofenac ((2.7 ± 0.7) × 107 M–1 s–1), atrazine ((5.7 ± 0.1) × 106 M–1 s–1), carbamazepine ((4.2 ± 0.01) × 106 M–1 s–1), and ibuprofen ((1.2 ± 1.1) × 106 M–1 s–1). Contributions from UV, reactive nitrogen species (RNS), hydroxyl radical (•OH), and CO3•– to the CEC decomposition in UV/NO3– in the presence and absence of HCO3– were investigated. In addition, possible transformation products and degradation pathways of triclosan, diclofenac, bisphenol A, and estrone in UV/NO3–/HCO3– were proposed based on the mass (MS) and MS2 spectra. Significant reduction in the cytotoxicity of bisphenol A was observed after the treatment with UV/NO3–/HCO3–." @default.
• W2895585370 created "2018-10-12" @default.
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• W2895585370 date "2018-10-04" @default.
• W2895585370 modified "2023-10-14" @default.
• W2895585370 title "Effects of HCO₃^– on Degradation of Toxic Contaminants of Emerging Concern by UV/NO₃^–" @default.
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• W2895585370 doi "https://doi.org/10.1021/acs.est.8b04383" @default.
• W2895585370 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30284820" @default.
• W2895585370 hasPublicationYear "2018" @default.
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