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- W2895598422 abstract "Previous theoretical reports have described the oxidation of few-layer black phosphorus and its effects on the electronic properties. Theoretically, native oxide layers bring opportunities for band gap engineering, but the detection of the different types of oxides is still a challenge at the experimental level. In this work, we uncover a correlation between thermal processes and Raman shift for the Ag1, B2g, and Ag2 vibrational modes. The thermal expansion coefficients (temperature range, 290-485 K) for the Ag1, B2g, and Ag2 were -0.015, -0.027, and -0.028 cm-1 K-1, respectively. Differential scanning calorimetry analysis shows an endothermic process centered at 528 K, and it was related with a mass increase according to thermogravimetric analysis. Raman shift temperature dependence was correlated to theoretical lattice thermal expansion, and a significant deviation was detected in the stacking direction at 500 K." @default.
- W2895598422 created "2018-10-12" @default.
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- W2895598422 date "2018-10-03" @default.
- W2895598422 modified "2023-10-16" @default.
- W2895598422 title "Quantitative Tracking of the Oxidation of Black Phosphorus in the Few-Layer Regime" @default.
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- W2895598422 doi "https://doi.org/10.1021/acsomega.8b01989" @default.
- W2895598422 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6644649" @default.
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