Matches in SemOpenAlex for { <https://semopenalex.org/work/W2895599215> ?p ?o ?g. }
- W2895599215 endingPage "8" @default.
- W2895599215 startingPage "1" @default.
- W2895599215 abstract "New platinum(IV) complexes containing N2S2 donor atoms were synthesized by the reactions of [Pt(p-MeC6H4)2(SMe2)2] and [PtCl2(DMSO)2] with 2,2′-dithiopyridine (dtp) in 1:1 M ratio. In these reactions, 2-mercaptopyridine (mpy) ligands were formed through the cleavage of the disulfide bond in 2,2′-dithiopyridine. The mpy ligands were coordinated to the platinum center via the nitrogen and sulfur atoms and the obtained platinum(IV) complexes exhibited octahedral geometry. The complexes were characterized by FT-IR, 1H NMR, UV–Vis, elemental analyses and conductometry. The crystal structure of the arylplatinum(IV) complex containing C2N2S2 donor atoms was determined by single crystal X-ray diffraction. The obtained molar conductance values revealed that the platinum(IV) complexes were nonelectrolytes. The interactions of the complexes with calf thymus DNA (CT-DNA) were investigated by absorption and fluorescence spectroscopy, cyclic voltammetry and viscometry methods. The intrinsic binding constants (Kb) of the complexes with CT-DNA, obtained from UV–Vis absorption data, were 9.60 × 104 M−1 and 11.56 × 104 M−1. Furthermore, the enthalpy and entropy of the interaction between the platinum(IV) complexes and CT-DNA were calculated. The obtained data revealed positive enthalpy and entropy changes indicating a hydrophobic interaction between these complexes and CT-DNA." @default.
- W2895599215 created "2018-10-12" @default.
- W2895599215 creator A5048306106 @default.
- W2895599215 creator A5072283425 @default.
- W2895599215 creator A5089758038 @default.
- W2895599215 date "2019-01-01" @default.
- W2895599215 modified "2023-10-16" @default.
- W2895599215 title "Synthesis of new platinum(IV) complexes through breaking disulfide bond; crystal structure determination, electrochemical, photoluminescence and DNA interaction investigation" @default.
- W2895599215 cites W1475405882 @default.
- W2895599215 cites W1480834102 @default.
- W2895599215 cites W1649806549 @default.
- W2895599215 cites W181292466 @default.
- W2895599215 cites W1983009271 @default.
- W2895599215 cites W1985699187 @default.
- W2895599215 cites W1991892007 @default.
- W2895599215 cites W1997731361 @default.
- W2895599215 cites W1998644325 @default.
- W2895599215 cites W2004999486 @default.
- W2895599215 cites W2008188908 @default.
- W2895599215 cites W2010633665 @default.
- W2895599215 cites W2013652499 @default.
- W2895599215 cites W2025692229 @default.
- W2895599215 cites W2056116492 @default.
- W2895599215 cites W2062620528 @default.
- W2895599215 cites W2068509261 @default.
- W2895599215 cites W2074487608 @default.
- W2895599215 cites W2084464821 @default.
- W2895599215 cites W2090858808 @default.
- W2895599215 cites W2095357376 @default.
- W2895599215 cites W2113559392 @default.
- W2895599215 cites W2130333210 @default.
- W2895599215 cites W2142594455 @default.
- W2895599215 cites W2152745328 @default.
- W2895599215 cites W2166302315 @default.
- W2895599215 cites W2282989227 @default.
- W2895599215 cites W2308586643 @default.
- W2895599215 cites W2334138351 @default.
- W2895599215 cites W2464288896 @default.
- W2895599215 cites W2513202150 @default.
- W2895599215 cites W2782597535 @default.
- W2895599215 cites W2952225863 @default.
- W2895599215 cites W602212531 @default.
- W2895599215 doi "https://doi.org/10.1016/j.ica.2018.10.007" @default.
- W2895599215 hasPublicationYear "2019" @default.
- W2895599215 type Work @default.
- W2895599215 sameAs 2895599215 @default.
- W2895599215 citedByCount "9" @default.
- W2895599215 countsByYear W28955992152019 @default.
- W2895599215 countsByYear W28955992152020 @default.
- W2895599215 countsByYear W28955992152021 @default.
- W2895599215 countsByYear W28955992152022 @default.
- W2895599215 countsByYear W28955992152023 @default.
- W2895599215 crossrefType "journal-article" @default.
- W2895599215 hasAuthorship W2895599215A5048306106 @default.
- W2895599215 hasAuthorship W2895599215A5072283425 @default.
- W2895599215 hasAuthorship W2895599215A5089758038 @default.
- W2895599215 hasConcept C115624301 @default.
- W2895599215 hasConcept C121332964 @default.
- W2895599215 hasConcept C147789679 @default.
- W2895599215 hasConcept C161790260 @default.
- W2895599215 hasConcept C17525397 @default.
- W2895599215 hasConcept C178790620 @default.
- W2895599215 hasConcept C179104552 @default.
- W2895599215 hasConcept C185592680 @default.
- W2895599215 hasConcept C2777869211 @default.
- W2895599215 hasConcept C3288061 @default.
- W2895599215 hasConcept C518104683 @default.
- W2895599215 hasConcept C52859227 @default.
- W2895599215 hasConcept C62520636 @default.
- W2895599215 hasConcept C70468152 @default.
- W2895599215 hasConcept C8010536 @default.
- W2895599215 hasConceptScore W2895599215C115624301 @default.
- W2895599215 hasConceptScore W2895599215C121332964 @default.
- W2895599215 hasConceptScore W2895599215C147789679 @default.
- W2895599215 hasConceptScore W2895599215C161790260 @default.
- W2895599215 hasConceptScore W2895599215C17525397 @default.
- W2895599215 hasConceptScore W2895599215C178790620 @default.
- W2895599215 hasConceptScore W2895599215C179104552 @default.
- W2895599215 hasConceptScore W2895599215C185592680 @default.
- W2895599215 hasConceptScore W2895599215C2777869211 @default.
- W2895599215 hasConceptScore W2895599215C3288061 @default.
- W2895599215 hasConceptScore W2895599215C518104683 @default.
- W2895599215 hasConceptScore W2895599215C52859227 @default.
- W2895599215 hasConceptScore W2895599215C62520636 @default.
- W2895599215 hasConceptScore W2895599215C70468152 @default.
- W2895599215 hasConceptScore W2895599215C8010536 @default.
- W2895599215 hasLocation W28955992151 @default.
- W2895599215 hasOpenAccess W2895599215 @default.
- W2895599215 hasPrimaryLocation W28955992151 @default.
- W2895599215 hasRelatedWork W1980601427 @default.
- W2895599215 hasRelatedWork W2000578039 @default.
- W2895599215 hasRelatedWork W2063826068 @default.
- W2895599215 hasRelatedWork W2072942862 @default.
- W2895599215 hasRelatedWork W2075931211 @default.
- W2895599215 hasRelatedWork W2089301926 @default.
- W2895599215 hasRelatedWork W2160761324 @default.
- W2895599215 hasRelatedWork W2442029984 @default.
- W2895599215 hasRelatedWork W3022386776 @default.