Matches in SemOpenAlex for { <https://semopenalex.org/work/W2895728801> ?p ?o ?g. }
- W2895728801 abstract "Abstract It is demonstrated that systematic and designated control of supramolecular nanostructures via interfacial engineering enables (opto)electronic C 60 ‐material properties to be widely adjusted. Interestingly, the lowest unoccupied molecular orbital (LUMO) energies of the same amphiphilic fullerene species are tuned up to 120 meV using supramolecular assembly, competitive to complete molecular change; cf. PC 61 BM to PC 71 BM causes a change of 200 meV. Morphology control is achieved through different thin‐film production techniques involving molecular assembly at interfaces, including liquid–liquid interfacial precipitation (LLIP), and Langmuir–Blodgett technique at air–water interface. LLIP enables supramolecularly ordered extended surfaces, yielding the least electronically stable LUMO ( E LUMO = −4.28 eV). After qualitatively explaining the observed electrochemical LUMO energy variation for these assemblies with varied molecular packing and aggregate dimensions, an analytical equation is proposed, connecting morphological parameters with LUMO energies with prospects in supramolecular chemistry. To demonstrate the applicability of supramolecular structure–electronic property relations and of supramolecular structure fabrication protocols established in this work to tailor device properties, amorphous‐Si/fullerene hybrid solar cells are built and characterized. It is found that the supramolecular structure variation can be successfully translated to the solar cells, giving rise to a prototype linear relation between LUMO energy and open‐circuit voltage." @default.
- W2895728801 created "2018-10-12" @default.
- W2895728801 creator A5013233663 @default.
- W2895728801 creator A5018716313 @default.
- W2895728801 creator A5020782898 @default.
- W2895728801 creator A5025570395 @default.
- W2895728801 creator A5034506337 @default.
- W2895728801 creator A5035977537 @default.
- W2895728801 creator A5036237574 @default.
- W2895728801 creator A5040024358 @default.
- W2895728801 creator A5057349354 @default.
- W2895728801 creator A5059470146 @default.
- W2895728801 creator A5063871016 @default.
- W2895728801 creator A5078051530 @default.
- W2895728801 creator A5082312178 @default.
- W2895728801 creator A5087026021 @default.
- W2895728801 date "2018-10-04" @default.
- W2895728801 modified "2023-10-16" @default.
- W2895728801 title "Controlling Intermolecular Interactions at Interfaces: Case of Supramolecular Tuning of Fullerene's Electronic Structure" @default.
- W2895728801 cites W1551699967 @default.
- W2895728801 cites W1893106939 @default.
- W2895728801 cites W1963501821 @default.
- W2895728801 cites W1967440083 @default.
- W2895728801 cites W1969827940 @default.
- W2895728801 cites W1973095190 @default.
- W2895728801 cites W1981934547 @default.
- W2895728801 cites W1986067518 @default.
- W2895728801 cites W1987904536 @default.
- W2895728801 cites W1988091937 @default.
- W2895728801 cites W1992320300 @default.
- W2895728801 cites W1995315712 @default.
- W2895728801 cites W2000479990 @default.
- W2895728801 cites W2002120633 @default.
- W2895728801 cites W2003873180 @default.
- W2895728801 cites W2010906558 @default.
- W2895728801 cites W2020163770 @default.
- W2895728801 cites W2020233336 @default.
- W2895728801 cites W2020816147 @default.
- W2895728801 cites W2024954708 @default.
- W2895728801 cites W2029107376 @default.
- W2895728801 cites W2040249613 @default.
- W2895728801 cites W2041038025 @default.
- W2895728801 cites W2043415890 @default.
- W2895728801 cites W2046309141 @default.
- W2895728801 cites W2048858238 @default.
- W2895728801 cites W2050117996 @default.
- W2895728801 cites W2054220330 @default.
- W2895728801 cites W2054340674 @default.
- W2895728801 cites W2054810869 @default.
- W2895728801 cites W2054898241 @default.
- W2895728801 cites W2055563809 @default.
- W2895728801 cites W2055688907 @default.
- W2895728801 cites W2059394374 @default.
- W2895728801 cites W2082917439 @default.
- W2895728801 cites W2084525909 @default.
- W2895728801 cites W2086628113 @default.
- W2895728801 cites W2090493368 @default.
- W2895728801 cites W2092024458 @default.
- W2895728801 cites W2094037665 @default.
- W2895728801 cites W2095186795 @default.
- W2895728801 cites W2113261130 @default.
- W2895728801 cites W2132012759 @default.
- W2895728801 cites W2140910555 @default.
- W2895728801 cites W2142634543 @default.
- W2895728801 cites W2146259503 @default.
- W2895728801 cites W2150788377 @default.
- W2895728801 cites W2157866962 @default.
- W2895728801 cites W2160072131 @default.
- W2895728801 cites W2160147117 @default.
- W2895728801 cites W2168347221 @default.
- W2895728801 cites W2171837061 @default.
- W2895728801 cites W2182423189 @default.
- W2895728801 cites W2189622474 @default.
- W2895728801 cites W2195715669 @default.
- W2895728801 cites W2199313381 @default.
- W2895728801 cites W2229109093 @default.
- W2895728801 cites W2239190235 @default.
- W2895728801 cites W2246610016 @default.
- W2895728801 cites W2264440646 @default.
- W2895728801 cites W2312703666 @default.
- W2895728801 cites W2313660338 @default.
- W2895728801 cites W2319785588 @default.
- W2895728801 cites W2324858601 @default.
- W2895728801 cites W2335472506 @default.
- W2895728801 cites W2472218537 @default.
- W2895728801 cites W2488516495 @default.
- W2895728801 cites W2508936693 @default.
- W2895728801 cites W2514160335 @default.
- W2895728801 cites W2527448075 @default.
- W2895728801 cites W2610582314 @default.
- W2895728801 cites W2738669496 @default.
- W2895728801 cites W2769467666 @default.
- W2895728801 cites W2782519314 @default.
- W2895728801 cites W3187163767 @default.
- W2895728801 doi "https://doi.org/10.1002/aenm.201801737" @default.
- W2895728801 hasPublicationYear "2018" @default.
- W2895728801 type Work @default.
- W2895728801 sameAs 2895728801 @default.
- W2895728801 citedByCount "17" @default.
- W2895728801 countsByYear W28957288012018 @default.