Matches in SemOpenAlex for { <https://semopenalex.org/work/W2895743119> ?p ?o ?g. }
- W2895743119 abstract "The topochemical transformation of single crystals of ${mathrm{Sr}}_{3}{mathrm{Ir}}_{2}{mathrm{O}}_{7}$ into ${mathrm{Sr}}_{3}{mathrm{Ir}}_{2}{mathrm{O}}_{7}{mathrm{F}}_{2}$ is reported via fluorine insertion. Characterization of the newly formed ${mathrm{Sr}}_{3}{mathrm{Ir}}_{2}{mathrm{O}}_{7}{mathrm{F}}_{2}$ phase shows a nearly complete oxidation of ${mathrm{Ir}}^{4+}$ cations into ${mathrm{Ir}}^{5+}$ that in turn drives the system from an antiferromagnetic Mott insulator with a half-filled ${J}_{mathrm{eff}}=1/2$ band into a nonmagnetic $J=0$ band insulator. First principles calculations reveal a remarkably flat insertion energy that locally drives the fluorination process to completion. Band structure calculations support the formation of a band insulator whose charge gap relies on the strong spin-orbit coupling inherent in the Ir metal ions of this compound." @default.
- W2895743119 created "2018-10-12" @default.
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- W2895743119 date "2018-10-16" @default.
- W2895743119 modified "2023-10-16" @default.
- W2895743119 title "<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:msub><mml:mi>Sr</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:msub><mml:mi>Ir</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi mathvariant=normal>O</mml:mi><mml:mn>7</mml:mn></mml:msub><mml:msub><mml:mi mathvariant=normal>F</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:mrow></mml:math> : Topochemical conversion of a relativistic Mott state into a spin-orbit driven band insulator" @default.
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- W2895743119 doi "https://doi.org/10.1103/physrevb.98.155128" @default.
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