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• W2895798565 endingPage "6969" @default.
• W2895798565 startingPage "6965" @default.
• W2895798565 abstract "The unique cyclization of benzamide derivatives that contain an alkyne by a Pd(0)/dialkyl(biaryl)phosphine catalytic system is reported. The reaction efficiently provides a variety of six-membered N-heterocyclic compounds that contain a fully substituted carbon center without the need for a stoichiometric additive. Mechanistic studies suggest that this unprecedented cyclization starts with the cleavage of a propargylic C–O bond, and a 1,3-diene has been identified as a relevant intermediate." @default.
• W2895798565 created "2018-10-26" @default.
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• W2895798565 date "2018-10-23" @default.
• W2895798565 modified "2023-09-25" @default.
• W2895798565 title "Construction of <i>N</i>-Heterocyclic Systems Containing a Fully Substituted Allylic Carbon by Palladium/Phosphine Catalysis" @default.
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• W2895798565 doi "https://doi.org/10.1021/acs.orglett.8b03127" @default.
• W2895798565 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30351960" @default.
• W2895798565 hasPublicationYear "2018" @default.
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