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- W2895810834 abstract "The thermal stability of ErAs nanoparticles and bulk-like powders, synthesized by pulsed laser ablation and direct reaction, respectively, is investigated up to 700 °C in N2. Thermogravimetric analysis and XRD are used to monitor the decomposition temperatures and crystalline compositions of the synthesized powders, respectively. Degradation of unagglomerated nanoparticle powders is observed at 350 °C accompanied by the crystallization of amorphous Er2O3. Mass balance analysis suggests that the mass loss occurs as a result of arsenic volatilization rather than congruent sublimation of ErAs. Conversely, micron-sized agglomerated particles grown by direct reaction show little evidence for degradation under similar thermal processing conditions. This significant decrease in ErAs stability compared to agglomerated powders suggests a size dependence on the degradation characteristics of ErAs." @default.
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- W2895810834 date "2018-10-15" @default.
- W2895810834 modified "2023-09-26" @default.
- W2895810834 title "Size dependent arsenic volatilization in ErAs nanoparticle powders" @default.
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- W2895810834 doi "https://doi.org/10.1063/1.5048191" @default.
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