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• W2895814060 abstract "The aqueous self-assembly behavior of a series of poly(ethylene glycol)-poly(l-/d-lactide) block copolymers and corresponding stereocomplexes is examined by differential scanning calorimetry, dynamic light scattering, and transmission electron microscopy. Block copolymers assemble into spherical micelles and worm-like aggregates at room temperature, whereby the fraction of the latter seemingly increases with decreasing lactide weight fraction or hydrophobicity. The formation of the worm-like aggregates arises from the crystallization of the polylactide by which the spherical micelles become colloidally unstable and fuse epitaxically with other micelles. The self-assembly behavior of the stereocomplex aggregates is found to be different from that of the block copolymers, resulting in rather irregular-shaped clusters of spherical micelles and pearl-necklace-like structures." @default.
• W2895814060 created "2018-10-26" @default.
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• W2895814060 date "2018-10-15" @default.
• W2895814060 modified "2023-10-10" @default.
• W2895814060 title "Polylactide‐Based Amphiphilic Block Copolymers: Crystallization‐Induced Self‐Assembly and Stereocomplexation" @default.
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• W2895814060 doi "https://doi.org/10.1002/marc.201800639" @default.
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