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- W2895819613 abstract "The formation of NbOCl3 and TaOCl3 and their adsorption behavior on quartz surfaces was explored by applying an isothermal gas-chromatographic method. Trace amounts of short-lived Nb and Ta isotopes were used. Adsorption enthalpy values (ΔHads) at zero surface coverage of –ΔHads(NbOCl3) = 102 ± 4 kJ/mol and –ΔHads(TaOCl3) = 128 ± 5 kJ/mol were determined by analyzing the chromatographic behavior of the Nb and Ta complexes with a Monte-Carlo simulation method based on an adsorption–desorption kinetic model. By applying an empirical correlation, the experimental ΔHads values were successively related to the macroscopic standard sublimation enthalpy, ΔH°subl, as a measure of the volatility of each substance. The inferred sublimation enthalpies are in agreement with tabulated thermochemical values. Thus, the linear empirical correlation between ΔHads and ΔH°subl for metal-oxychlorides was updated with the inclusion of the present data. According to the predicted ΔH°subl(DbOCl3), a ΔHads(DbOCl3) value of 135 ± 2 kJ/mol was extrapolated. The future accomplishment of comparative studies with DbOCl3 under the same experimental conditions will provide valuable information on the volatility trend in Group-5 elements, together with an indication on the magnitude of relativistic effects on the electronic structure of dubnium." @default.
- W2895819613 created "2018-10-26" @default.
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- W2895819613 date "2019-02-01" @default.
- W2895819613 modified "2023-09-25" @default.
- W2895819613 title "Formation and thermochemical properties of oxychlorides of niobium (Nb) and tantalum (Ta): Towards the gas-phase investigation of dubnium (Db) oxychloride" @default.
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- W2895819613 doi "https://doi.org/10.1016/j.ica.2018.10.032" @default.
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