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• W2895835462 abstract "The two‐dimensional (2D) cobalt‐carboxylate framework of the hxl type with the formula [Co 3 (bdc) 3 (DMA) 3 ] · DMA was synthesized in a mixture of the ionic liquid 1‐butyl‐3‐methylimidazolium tetrafluoroborate [BMIm][BF 4 ], HBF 4 and N , N ‐dimethylacetamide (DMA) via solvothermal reaction. The structure of [Co 3 (bdc) 3 (DMA) 3 ] · DMA (bdc 2– = benzene‐1,4‐dicarboxylate) consists of an hourglass trinuclear secondary building unit (SBU) with the first octahedral (oct)‐octahedral and square‐pyramidal (sq‐pyr) coordinated cobalt atoms in the sequence Co oct –Co oct –Co sq‐pyr with terminally coordinated DMA molecules. These SBUs are bridged by six bdc 2– ligands into a two‐dimensional layered structure." @default.
• W2895835462 created "2018-10-26" @default.
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• W2895835462 date "2018-10-09" @default.
• W2895835462 modified "2023-09-25" @default.
• W2895835462 title "Two-dimensional Cobalt-Carboxylate Framework with Hourglass Trinuclear Co₃ (COO)₆ (DMA)₃ Secondary Building Unit" @default.
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• W2895835462 doi "https://doi.org/10.1002/zaac.201800330" @default.
• W2895835462 hasPublicationYear "2018" @default.
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