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• W2895854367 abstract "Abstract Tb-substituted layered double hydroxides (Tb-LDHs) with NO3− in the interlayer were synthesized by a hydrothermal method and then used to capture and sense CO32− in aqueous solution. X-ray diffractometry confirmed that single-phase Tb-LDHs with Tb contents of 1–5 mol% were successfully synthesized. The NO3− ions of 5 mol% Tb-substituted LDH (Tb5LDH) were exchanged by CO32− ions in a Na2CO3 aqueous solution at pH = 11. The ion exchange for Tb5LDH was promoted with increasing the concentration of the Na2CO3 solution. Photoluminescence spectroscopy revealed that Tb5LDH with CO32− in the interlayer displayed an excitation wavelength of 229 nm and exhibited a green emission signal originating from the 4f8 → 4f75d1 transition, 5D4 → 7FJ (J = 3, 4, 5, 6), in the range of 400–700 nm. The intensity of the emission signal of the ion-exchanged Tb5LDH excited at 229 nm increased with increasing the content of CO32− in Tb5LDH. These results indicate that Tb5LDH was capable of capturing and sensing CO32− dissolved in water by irradiation with 229-nm light." @default.
• W2895854367 created "2018-10-26" @default.
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• W2895854367 date "2019-02-01" @default.
• W2895854367 modified "2023-10-17" @default.
• W2895854367 title "Photoluminescence changes of Tb-substituted layered double hydroxides caused by capturing carbonate ions in water" @default.
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• W2895854367 doi "https://doi.org/10.1016/j.materresbull.2018.10.021" @default.
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