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- W2895854811 abstract "Abstract A highly selective and efficient oxidative carbocyclization/borylation of enallenols catalyzed by palladium immobilized on amino‐functionalized siliceous mesocellular foam (Pd‐AmP‐MCF) was developed for diastereoselective cyclobutenol synthesis. The heterogeneous palladium catalyst can be recovered and recycled without any observed loss of activity or selectivity. The high diastereoselectivity of the reaction is proposed to originate from a directing effect of the enallenol hydroxyl group. Optically pure cyclobutenol synthesis was achieved by the heterogeneous strategy by using chiral enallenol obtained from kinetic resolution." @default.
- W2895854811 created "2018-10-26" @default.
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- W2895854811 date "2018-11-05" @default.
- W2895854811 modified "2023-10-02" @default.
- W2895854811 title "Diastereoselective Cyclobutenol Synthesis: A Heterogeneous Palladium‐Catalyzed Oxidative Carbocyclization‐Borylation of Enallenols" @default.
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- W2895854811 doi "https://doi.org/10.1002/chem.201805118" @default.
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