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- W2895861541 abstract "Abstract Total synthesis of the revised cryptorigidifoliol K and 2′‐ epi ‐cryptorigidifoliol K was accomplished. Salient features of the synthesis involve tandem isomerization followed by C−O and C−C bond forming reaction, iodolactonization and Nozaki‐Hiyama‐Kishi reaction. The synthesis allowed for confirmation of the structure as well as the elucidation of the unassigned stereocenter present in the side chain of the revised structure by correlating the spectral and analytical data of the synthetic cryptorigidifoliol K and 2′‐ epi ‐cryptorigidifoliol K with the natural product data, which was found to be 1 S ,5 R ,7 S ,2′ R ,3′ E ." @default.
- W2895861541 created "2018-10-26" @default.
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- W2895861541 date "2018-10-30" @default.
- W2895861541 modified "2023-10-18" @default.
- W2895861541 title "Total Synthesis of Cryptorigidifoliol K: Confirmation of Structure and Absolute Configuration" @default.
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- W2895861541 doi "https://doi.org/10.1002/ajoc.201800522" @default.
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