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• W2895864724 endingPage "6595" @default.
• W2895864724 startingPage "6591" @default.
• W2895864724 abstract "A diastereoselective construction of biologically important tetrahydrocyclopenta[b]naphthalene derivatives has been achieved via a phosphine-catalyzed [3 + 2] annulation of 2-hydroxy-1,4-naphthaquinone derivatives and allenoate. Various tetrahydrocyclopenta[b]naphthalene derivatives containing contiguous quaternary carbon centers are obtained in good yields with excellent diastereoselectivities. The asymmetric version gave the chiral product in up to 57% ee under catalysis of Kwon chiral phosphine. The reaction undergoes a reaction mechanism involving consecutive γ-addition–aldol reaction." @default.
• W2895864724 created "2018-10-26" @default.
• W2895864724 creator A5004016253 @default.
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• W2895864724 creator A5091836844 @default.
• W2895864724 date "2018-10-10" @default.
• W2895864724 modified "2023-10-16" @default.
• W2895864724 title "Phosphine-Catalyzed [3 + 2] Annulation of 2-Hydroxy-1,4-naphthaquinones and Allenoate: An Allene–Alkene [3 + 2] Annulation Mechanism Involving Consecutive γ-Addition–Aldol Reaction" @default.
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• W2895864724 doi "https://doi.org/10.1021/acs.orglett.8b02947" @default.
• W2895864724 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30303016" @default.
• W2895864724 hasPublicationYear "2018" @default.

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