Matches in SemOpenAlex for { <https://semopenalex.org/work/W2895871882> ?p ?o ?g. }
- W2895871882 endingPage "38557" @default.
- W2895871882 startingPage "38547" @default.
- W2895871882 abstract "In this work, we report a novel application of chemical vapor deposition (CVD) in which the calcination and reduction of Cu(thd)2 deposited onto 4.9 wt % Cu/SiO2 induces significant decomposition of 28 nm crystalline Cu into ultrasmall ∼2 nm particles (5.1 wt % Cu/SiO2). The Cu loading slightly increased, but the particle size dramatically decreased. The deposition of Cu(thd)2 onto the Cu surface can initially affect the size reduction of the metallic Cu particles due to charge transfer between Cu(thd)2 and the Cu surface. Thermal treatments, including calcination in air and reduction in H2, can further influence the Cu particle decomposition. The mechanism of change in the Cu particle decomposition was investigated by a variety of experiments, such as X-ray diffraction and in situ X-ray absorption spectroscopy. CVD treatment of Cu/SiO2 can create Cu-rich sites, which effectively enhance the conversion and acrolein yield in selective propylene oxidation. The intermediate associated with propylene oxidation on the Cu catalysts was also examined by IR spectroscopy." @default.
- W2895871882 created "2018-10-26" @default.
- W2895871882 creator A5005282508 @default.
- W2895871882 creator A5009664001 @default.
- W2895871882 creator A5012165104 @default.
- W2895871882 creator A5020365692 @default.
- W2895871882 creator A5028459646 @default.
- W2895871882 date "2018-10-15" @default.
- W2895871882 modified "2023-10-16" @default.
- W2895871882 title "Decomposition of Large Cu Crystals into Ultrasmall Particles Using Chemical Vapor Deposition and Their Application in Selective Propylene Oxidation" @default.
- W2895871882 cites W1555450157 @default.
- W2895871882 cites W1616665557 @default.
- W2895871882 cites W1875891306 @default.
- W2895871882 cites W1967749052 @default.
- W2895871882 cites W1974583786 @default.
- W2895871882 cites W1979852826 @default.
- W2895871882 cites W1984677438 @default.
- W2895871882 cites W1984866899 @default.
- W2895871882 cites W1989685122 @default.
- W2895871882 cites W1990554271 @default.
- W2895871882 cites W1994540310 @default.
- W2895871882 cites W1995695718 @default.
- W2895871882 cites W1996682792 @default.
- W2895871882 cites W2014574043 @default.
- W2895871882 cites W2014824706 @default.
- W2895871882 cites W2016136557 @default.
- W2895871882 cites W2016465254 @default.
- W2895871882 cites W2024498209 @default.
- W2895871882 cites W2026417219 @default.
- W2895871882 cites W2037660969 @default.
- W2895871882 cites W2045743544 @default.
- W2895871882 cites W2051130277 @default.
- W2895871882 cites W2059054717 @default.
- W2895871882 cites W2059577436 @default.
- W2895871882 cites W2061076880 @default.
- W2895871882 cites W2062997937 @default.
- W2895871882 cites W2069946148 @default.
- W2895871882 cites W2073601391 @default.
- W2895871882 cites W2082415642 @default.
- W2895871882 cites W2085170064 @default.
- W2895871882 cites W2088059049 @default.
- W2895871882 cites W2090736293 @default.
- W2895871882 cites W2101705789 @default.
- W2895871882 cites W2112165279 @default.
- W2895871882 cites W2123746383 @default.
- W2895871882 cites W2134716155 @default.
- W2895871882 cites W2159535735 @default.
- W2895871882 cites W2166766557 @default.
- W2895871882 cites W2171543447 @default.
- W2895871882 cites W2257762244 @default.
- W2895871882 cites W2300323386 @default.
- W2895871882 cites W2313779008 @default.
- W2895871882 cites W2318236736 @default.
- W2895871882 cites W2322023167 @default.
- W2895871882 cites W2323292038 @default.
- W2895871882 cites W2325029536 @default.
- W2895871882 cites W2325535163 @default.
- W2895871882 cites W2331832249 @default.
- W2895871882 cites W2333483639 @default.
- W2895871882 cites W2510292469 @default.
- W2895871882 cites W2579875715 @default.
- W2895871882 cites W2759128002 @default.
- W2895871882 doi "https://doi.org/10.1021/acsami.8b10534" @default.
- W2895871882 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30360110" @default.
- W2895871882 hasPublicationYear "2018" @default.
- W2895871882 type Work @default.
- W2895871882 sameAs 2895871882 @default.
- W2895871882 citedByCount "8" @default.
- W2895871882 countsByYear W28958718822019 @default.
- W2895871882 countsByYear W28958718822020 @default.
- W2895871882 countsByYear W28958718822021 @default.
- W2895871882 countsByYear W28958718822022 @default.
- W2895871882 crossrefType "journal-article" @default.
- W2895871882 hasAuthorship W2895871882A5005282508 @default.
- W2895871882 hasAuthorship W2895871882A5009664001 @default.
- W2895871882 hasAuthorship W2895871882A5012165104 @default.
- W2895871882 hasAuthorship W2895871882A5020365692 @default.
- W2895871882 hasAuthorship W2895871882A5028459646 @default.
- W2895871882 hasConcept C111368507 @default.
- W2895871882 hasConcept C124681953 @default.
- W2895871882 hasConcept C127313418 @default.
- W2895871882 hasConcept C127413603 @default.
- W2895871882 hasConcept C151730666 @default.
- W2895871882 hasConcept C160434732 @default.
- W2895871882 hasConcept C161790260 @default.
- W2895871882 hasConcept C171250308 @default.
- W2895871882 hasConcept C178790620 @default.
- W2895871882 hasConcept C179104552 @default.
- W2895871882 hasConcept C185592680 @default.
- W2895871882 hasConcept C187530423 @default.
- W2895871882 hasConcept C191897082 @default.
- W2895871882 hasConcept C192562407 @default.
- W2895871882 hasConcept C2778517922 @default.
- W2895871882 hasConcept C2780422782 @default.
- W2895871882 hasConcept C2816523 @default.
- W2895871882 hasConcept C42360764 @default.
- W2895871882 hasConcept C544778455 @default.
- W2895871882 hasConcept C57410435 @default.