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• W2895883152 abstract "We report attenuated total reflection FTIR spectra of microcrystalline samples of M2(H2O)n(B12F12) (MNa, K, Rb, Cs) and Na2(H2O)6(B12Cl12). The ν(OH) bands are unusually narrow compared to the spectra of other alkali metal salt hydrates, with most full widths at half-max less than 20 cm−1 and some less than 10 cm−1. In addition, these bands are not as redshifted compared to the spectra of other alkali metal salt hydrates. These unusual effects are attributed to extremely weak OH⋯F and OH⋯Cl hydrogen bonding between the coordinated H2O molecules and the B12F122− and B12Cl122− superweak anions. The ν(OH) bands in these compounds are as narrow as the bands in the FTIR spectrum of monomeric H2O absorbed in poly(vinylidene fluoride), in which the only hydrogen bonding is OH⋯FC, or as the bands in the IR photodissociation spectrum of the gas-phase species [(Ar)Na(H2O)2]+. These unusual spectra are compared to the literature spectrum of [NEt4]4[Hg(CB11F11)2]2∙H2O, which also exhibits sharp ν(OH) bands with relatively small redshifts from the ν(OH) values for H2O(g)." @default.
• W2895883152 created "2018-10-26" @default.
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• W2895883152 date "2019-01-01" @default.
• W2895883152 modified "2023-10-18" @default.
• W2895883152 title "Unusually sharp FTIR ν(OH) bands and very weak O H⋯F hydrogen bonds in M2(H2O)1,2B12F12 hydrates (M Na Cs)" @default.
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• W2895883152 doi "https://doi.org/10.1016/j.jfluchem.2018.10.010" @default.
• W2895883152 hasPublicationYear "2019" @default.
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