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• W2895886158 abstract "An expedient route to the pentacyclic core of the tryptoquivaline alkaloids and the total synthesis of natural product (+)-3'-(4-oxoquinazolin-3-yl)spiro[1H-indole-3,5'-oxolane]-2,2'-dione (1) have been achieved. The route is enabled by a key, highly stereoselective, aldol reaction catalysed by a Ag(i) and cinchona-derived aminophosphine ligand system, forming a highly substituted oxazoline ring, and setting the C1 spirocyclic stereocentre for downstream manipulation." @default.
• W2895886158 created "2018-10-26" @default.
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• W2895886158 creator A5059540181 @default.
• W2895886158 date "2018-01-01" @default.
• W2895886158 modified "2023-10-01" @default.
• W2895886158 title "Catalytic stereoselective total synthesis of a spiro-oxindole alkaloid and the pentacyclic core of tryptoquivalines" @default.
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• W2895886158 doi "https://doi.org/10.1039/c8cc07479h" @default.
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