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- W2895899172 abstract "The reversible high-pressure phase transition in boron carbide, making this opaque solid glasslike transparent, the visualization of actual structural distortions in the form of atomic arrangements replacing the three-atomic chain in the unit cell, and the electronic DOS calculated for realistic structure models require re-interpretation of the well-known electronic transitions. – The excellent correlation with a selected distorted structure model, proposed by Ektarawong, assuming that the polar C atoms are randomly distributed over all polar sites of the icosahedra, suggests this model to be close to the actual structure. Assignment between electronic properties and structural peculiarities enables solving some open problems, for example, the nature of the high-pressure phase transition. According to Rasim, some boron-rich components replacing a certain share of three-atomic exhibit negative energies; thus they reduce the total energy and make B4.3C the most stable structure." @default.
- W2895899172 created "2018-10-26" @default.
- W2895899172 creator A5079083303 @default.
- W2895899172 date "2018-12-01" @default.
- W2895899172 modified "2023-10-16" @default.
- W2895899172 title "Assignment of the electronic transitions in B4.3C boron carbide implies a specifically distorted crystal structure" @default.
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- W2895899172 doi "https://doi.org/10.1016/j.solidstatesciences.2018.10.006" @default.
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