FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2895952196> ?p ?o ?g. }

• W2895952196 endingPage "468" @default.
• W2895952196 startingPage "460" @default.
• W2895952196 abstract "The oxidative carbonylation of alcohols to prepare corresponding dialkyl carbonates was investigated using alkali metal methylselenite [MSeO2(OCH3)] and alkali metal selenites (M2SeO3, M = Li, Na, K, Cs) as catalysts. Of various alcohols tested, methanol and 2-methoxyethanol (MEG) are found to be highly reactive, affording corresponding dialkyl carbonates in yields of more than 30%, which are significantly higher than those achieved with Cu-based catalysts under similar reaction conditions. XRD and GC-Mass analysis of the spent catalyst recovered from the M2SeO3-catalyzed reaction of methanol revealed that M2SeO3 was converted into elemental selenium and MHCO3 along with the formation of several selenium-containing by-products including malodorous dimethyldiselenide, 1,2-dimethoxydiselane, and O,Se-dimethyl carbonoselenoate. On the contrary, the oxidative carbonylation of MEG with K2SeO3 was highly selective toward the formation of bis(2-methoxyethyl) carbonate (BMEC), without producing any selenium-containing by-products. A plausible mechanism for the MSeO2(OCH3)- and M2SeO3-catalyzed oxidative carbonylation of MEG was suggested on the basis of mechanistic and experimental results." @default.
• W2895952196 created "2018-10-26" @default.
• W2895952196 creator A5003126558 @default.
• W2895952196 creator A5007158625 @default.
• W2895952196 creator A5009037489 @default.
• W2895952196 creator A5025154088 @default.
• W2895952196 creator A5054208180 @default.
• W2895952196 creator A5054377654 @default.
• W2895952196 creator A5065515540 @default.
• W2895952196 creator A5089740534 @default.
• W2895952196 creator A5091534600 @default.
• W2895952196 date "2019-03-01" @default.
• W2895952196 modified "2023-10-05" @default.
• W2895952196 title "Selenite-catalyzed oxidative carbonylation of alcohols to dialkyl carbonates" @default.
• W2895952196 cites W1520834010 @default.
• W2895952196 cites W188126306 @default.
• W2895952196 cites W1969327539 @default.
• W2895952196 cites W1982543565 @default.
• W2895952196 cites W1988723700 @default.
• W2895952196 cites W1989661885 @default.
• W2895952196 cites W1990678450 @default.
• W2895952196 cites W1994160110 @default.
• W2895952196 cites W2010602232 @default.
• W2895952196 cites W2012675110 @default.
• W2895952196 cites W2015863264 @default.
• W2895952196 cites W2016222883 @default.
• W2895952196 cites W2018701019 @default.
• W2895952196 cites W2022200004 @default.
• W2895952196 cites W2025224627 @default.
• W2895952196 cites W2045672763 @default.
• W2895952196 cites W2057297052 @default.
• W2895952196 cites W2065350677 @default.
• W2895952196 cites W2070094598 @default.
• W2895952196 cites W2078420289 @default.
• W2895952196 cites W2083403785 @default.
• W2895952196 cites W2094146972 @default.
• W2895952196 cites W2105878481 @default.
• W2895952196 cites W2107632152 @default.
• W2895952196 cites W2113385735 @default.
• W2895952196 cites W2130971948 @default.
• W2895952196 cites W2153617400 @default.
• W2895952196 cites W233330031 @default.
• W2895952196 cites W2337735058 @default.
• W2895952196 cites W2517511599 @default.
• W2895952196 cites W2571506817 @default.
• W2895952196 cites W2773740543 @default.
• W2895952196 cites W2952594103 @default.
• W2895952196 doi "https://doi.org/10.1016/j.apcatb.2018.10.026" @default.
• W2895952196 hasPublicationYear "2019" @default.
• W2895952196 type Work @default.
• W2895952196 sameAs 2895952196 @default.
• W2895952196 citedByCount "3" @default.
• W2895952196 countsByYear W28959521962020 @default.
• W2895952196 countsByYear W28959521962021 @default.
• W2895952196 countsByYear W28959521962023 @default.
• W2895952196 crossrefType "journal-article" @default.
• W2895952196 hasAuthorship W2895952196A5003126558 @default.
• W2895952196 hasAuthorship W2895952196A5007158625 @default.
• W2895952196 hasAuthorship W2895952196A5009037489 @default.
• W2895952196 hasAuthorship W2895952196A5025154088 @default.
• W2895952196 hasAuthorship W2895952196A5054208180 @default.
• W2895952196 hasAuthorship W2895952196A5054377654 @default.
• W2895952196 hasAuthorship W2895952196A5065515540 @default.
• W2895952196 hasAuthorship W2895952196A5089740534 @default.
• W2895952196 hasAuthorship W2895952196A5091534600 @default.
• W2895952196 hasConcept C161790260 @default.
• W2895952196 hasConcept C168382676 @default.
• W2895952196 hasConcept C178790620 @default.
• W2895952196 hasConcept C179104552 @default.
• W2895952196 hasConcept C185592680 @default.
• W2895952196 hasConcept C198091228 @default.
• W2895952196 hasConcept C2778197717 @default.
• W2895952196 hasConcept C2779607525 @default.
• W2895952196 hasConcept C512735826 @default.
• W2895952196 hasConcept C544153396 @default.
• W2895952196 hasConcept C553756173 @default.
• W2895952196 hasConcept C55493867 @default.
• W2895952196 hasConcept C57600042 @default.
• W2895952196 hasConceptScore W2895952196C161790260 @default.
• W2895952196 hasConceptScore W2895952196C168382676 @default.
• W2895952196 hasConceptScore W2895952196C178790620 @default.
• W2895952196 hasConceptScore W2895952196C179104552 @default.
• W2895952196 hasConceptScore W2895952196C185592680 @default.
• W2895952196 hasConceptScore W2895952196C198091228 @default.
• W2895952196 hasConceptScore W2895952196C2778197717 @default.
• W2895952196 hasConceptScore W2895952196C2779607525 @default.
• W2895952196 hasConceptScore W2895952196C512735826 @default.
• W2895952196 hasConceptScore W2895952196C544153396 @default.
• W2895952196 hasConceptScore W2895952196C553756173 @default.
• W2895952196 hasConceptScore W2895952196C55493867 @default.
• W2895952196 hasConceptScore W2895952196C57600042 @default.
• W2895952196 hasFunder F4320321408 @default.
• W2895952196 hasFunder F4320322120 @default.
• W2895952196 hasLocation W28959521961 @default.
• W2895952196 hasOpenAccess W2895952196 @default.
• W2895952196 hasPrimaryLocation W28959521961 @default.
• W2895952196 hasRelatedWork W2013356874 @default.
• W2895952196 hasRelatedWork W2048000703 @default.

• next