Matches in SemOpenAlex for { <https://semopenalex.org/work/W2895963017> ?p ?o ?g. }
- W2895963017 endingPage "25246" @default.
- W2895963017 startingPage "25237" @default.
- W2895963017 abstract "New highly concentrated electrolytes based on ether solvents were developed for sodium electrochemical cells. The investigated electrolytes use sodium triflate and glycol diether oligomers of different length to form the electrolyte. These electrolytes present conductivities that increase as a function of concentration even when the electrolyte is composed of a majority of ion pairs and aggregates. Correlation analysis between the electrolyte speciation and conductivity suggests the presence of two distinct mechanisms of charge transport, namely a traditional vehicular mechanism based on the diffusion of free ions and a hopping mechanism involving the making and breaking of ion-pairs and/or aggregates. The former mechanism represents the charge transport of glyme with 3 or 4 units, while the latter is observed in electrolytes composed of short chains, i.e., 1 or 2 units. The proposed mechanism of transport is corroborated via molecular dynamics simulations. In addition, our experiments demonstrate that the high concentration of the sodium salt not only increases the overall conductivity of the electrolyte but also does not affect its electrochemical window." @default.
- W2895963017 created "2018-10-26" @default.
- W2895963017 creator A5002245159 @default.
- W2895963017 creator A5013157574 @default.
- W2895963017 creator A5015575184 @default.
- W2895963017 creator A5032038547 @default.
- W2895963017 creator A5036956510 @default.
- W2895963017 creator A5070429589 @default.
- W2895963017 creator A5089736852 @default.
- W2895963017 date "2018-10-18" @default.
- W2895963017 modified "2023-10-17" @default.
- W2895963017 title "Mechanism behind the Unusually High Conductivities of High Concentrated Sodium Ion Glyme-Based Electrolytes" @default.
- W2895963017 cites W1964973908 @default.
- W2895963017 cites W2001120278 @default.
- W2895963017 cites W2003949305 @default.
- W2895963017 cites W2006982010 @default.
- W2895963017 cites W2019465613 @default.
- W2895963017 cites W2021172010 @default.
- W2895963017 cites W2028046413 @default.
- W2895963017 cites W2028106844 @default.
- W2895963017 cites W2028733168 @default.
- W2895963017 cites W2036490194 @default.
- W2895963017 cites W2037628624 @default.
- W2895963017 cites W2040959430 @default.
- W2895963017 cites W2045418943 @default.
- W2895963017 cites W2053142613 @default.
- W2895963017 cites W2067601560 @default.
- W2895963017 cites W2068350136 @default.
- W2895963017 cites W2081847447 @default.
- W2895963017 cites W2081948633 @default.
- W2895963017 cites W2089525884 @default.
- W2895963017 cites W2091875228 @default.
- W2895963017 cites W2092944857 @default.
- W2895963017 cites W2115461419 @default.
- W2895963017 cites W2154035368 @default.
- W2895963017 cites W2158863190 @default.
- W2895963017 cites W2163488339 @default.
- W2895963017 cites W2166446427 @default.
- W2895963017 cites W2227262265 @default.
- W2895963017 cites W2267758340 @default.
- W2895963017 cites W2318991903 @default.
- W2895963017 cites W2326431408 @default.
- W2895963017 cites W2333960047 @default.
- W2895963017 cites W2340013575 @default.
- W2895963017 cites W2341894171 @default.
- W2895963017 cites W2474193051 @default.
- W2895963017 cites W2514282141 @default.
- W2895963017 cites W2520699066 @default.
- W2895963017 cites W2558075146 @default.
- W2895963017 cites W2567950401 @default.
- W2895963017 cites W2583613881 @default.
- W2895963017 cites W2593941100 @default.
- W2895963017 cites W2603442821 @default.
- W2895963017 cites W2607281958 @default.
- W2895963017 cites W2724610509 @default.
- W2895963017 cites W2766824519 @default.
- W2895963017 cites W2770103241 @default.
- W2895963017 cites W2772015765 @default.
- W2895963017 cites W2781895724 @default.
- W2895963017 cites W2787546358 @default.
- W2895963017 cites W2803995556 @default.
- W2895963017 cites W3142428734 @default.
- W2895963017 cites W4300565850 @default.
- W2895963017 cites W583716941 @default.
- W2895963017 cites W653936870 @default.
- W2895963017 doi "https://doi.org/10.1021/acs.jpcc.8b06991" @default.
- W2895963017 hasPublicationYear "2018" @default.
- W2895963017 type Work @default.
- W2895963017 sameAs 2895963017 @default.
- W2895963017 citedByCount "17" @default.
- W2895963017 countsByYear W28959630172019 @default.
- W2895963017 countsByYear W28959630172020 @default.
- W2895963017 countsByYear W28959630172021 @default.
- W2895963017 countsByYear W28959630172022 @default.
- W2895963017 countsByYear W28959630172023 @default.
- W2895963017 crossrefType "journal-article" @default.
- W2895963017 hasAuthorship W2895963017A5002245159 @default.
- W2895963017 hasAuthorship W2895963017A5013157574 @default.
- W2895963017 hasAuthorship W2895963017A5015575184 @default.
- W2895963017 hasAuthorship W2895963017A5032038547 @default.
- W2895963017 hasAuthorship W2895963017A5036956510 @default.
- W2895963017 hasAuthorship W2895963017A5070429589 @default.
- W2895963017 hasAuthorship W2895963017A5089736852 @default.
- W2895963017 hasConcept C121332964 @default.
- W2895963017 hasConcept C131540310 @default.
- W2895963017 hasConcept C145148216 @default.
- W2895963017 hasConcept C147789679 @default.
- W2895963017 hasConcept C161790260 @default.
- W2895963017 hasConcept C17525397 @default.
- W2895963017 hasConcept C178790620 @default.
- W2895963017 hasConcept C179104552 @default.
- W2895963017 hasConcept C185592680 @default.
- W2895963017 hasConcept C21774173 @default.
- W2895963017 hasConcept C2776371256 @default.
- W2895963017 hasConcept C52859227 @default.
- W2895963017 hasConcept C537181965 @default.
- W2895963017 hasConcept C68801617 @default.
- W2895963017 hasConcept C69357855 @default.