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• W2895969135 abstract "Catalytic valorization of furfural (FUR) using a simple and low-cost metal catalyst has been considered as a hot topic in sustainable chemistry. In this work, a new [email protected] catalyst is prepared via the auto-combustion and in situ reduction method. When it is employed to promote the catalytic valorization of FUR in aliphatic alcohol, a nearly complete FUR conversion with excellent product selectivity is obtained under mild reaction conditions. Using methanol as reaction medium, the sole product is furfuryl alcohol (FA) in which ca. 99% yield of FA was attained. While, in ethanol, the obtained products mainly contain FA and furan-2-acrolein (FUA) in which a 94% conversion of FUR with a 91% total selectivity of FA and FUA was acquired. Based on the characterization of catalyst including XRD, SEM, XPS and H2-TPR techniques, it is concluded that the synergy effect of metal Ni and R-Ca crystal lattice plays a crucial role in the efficient conversion of FUR in aliphatic alcohol." @default.
• W2895969135 created "2018-10-26" @default.
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• W2895969135 date "2019-02-01" @default.
• W2895969135 modified "2023-09-27" @default.
• W2895969135 title "Highly efficient catalytic valorization of biomass-derived furfural in methanol and ethanol" @default.
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• W2895969135 doi "https://doi.org/10.1016/j.jiec.2018.10.009" @default.
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