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- W2895983185 abstract "An efficient and highly selective synthetic method toward the preparation of pillar[ n]arenes ( n = 5, 6) is reported, based upon a high solvent-dependent selectivity found in the condensation reaction between 1,4-dialkyloxybenzene and paraformaldehyde, involving methanesulfonic acid as catalyst. Pillar[6]arene (P6) is obtained as the major product when using chloroform as solvent, while in dichloromethane pillar[5]arene (P5) is the dominant product. Accordingly, a series of P5 and P6 have been selectively synthesized with excellent yield." @default.
- W2895983185 created "2018-10-26" @default.
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- W2895983185 date "2018-10-10" @default.
- W2895983185 modified "2023-10-14" @default.
- W2895983185 title "Highly Selective Synthesis of Pillar[<i>n</i>]arene (<i>n</i> = 5, 6)" @default.
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- W2895983185 doi "https://doi.org/10.1021/acs.orglett.8b02937" @default.
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