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- W2896030817 abstract "Abstract Thermal quenching is a common phenomenon hindering commercial applications of phosphors, and the relationship between matrix structure and thermal quenching is not yet clear especially for the red phosphor SrAl12O19:Mn4+. Here, we determined the energy levels of three types of Mn4+ sites in SrAl12O19 crystal structure based on the exchange-charge-model crystal field calculations and analyzed the Mn4+ ions preferential occupation combined with chemical bond covalence. The phosphor suffers from serious thermal quenching when the luminescence monitoring from 8 to 500 K was recorded. The combination of theoretical calculations and experimental verification also reveals that the symmetry and spatial distribution of octahedral sites for Mn4+ are crucial to better resistance to thermal quenching. This can be helpful to search for novel Mn4+ doped red phosphor with better resistance to thermal impact in the future." @default.
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- W2896030817 date "2019-02-01" @default.
- W2896030817 modified "2023-09-29" @default.
- W2896030817 title "Thermal quenching of Mn4+ luminescence in SrAl12O19:Mn4+" @default.
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- W2896030817 doi "https://doi.org/10.1016/j.jlumin.2018.10.044" @default.
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