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- W2896235895 endingPage "118" @default.
- W2896235895 startingPage "103" @default.
- W2896235895 abstract "A mechanistic study of a rhenium catalyzed monoalkylation of phenols is described. Reaction kinetics reveals a zero-order dependence on both alkene and phenol and a half order dependence on catalyst. Isotopic labeling studies, competition experiments, kinetic isotope effects, and Hammett analysis together afford experimental data consistent with a reversible C–H activation step and an irreversible hydrometalation process. The turnover-limiting step is identified as catalyst deaggregation. NMR studies of binary mixtures of catalyst and a single substrate (alkene or phenol) as well as those of reaction mixtures identify potential intermediates and off-cycle species. Despite the numerous Re complexes formed in these mixtures, the overall reaction is both high yielding and highly selective for monoalkylation of phenols." @default.
- W2896235895 created "2018-10-26" @default.
- W2896235895 creator A5032988856 @default.
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- W2896235895 creator A5085621143 @default.
- W2896235895 creator A5088374801 @default.
- W2896235895 date "2018-10-22" @default.
- W2896235895 modified "2023-10-09" @default.
- W2896235895 title "Mechanistic Study of a Re-Catalyzed Monoalkylation of Phenols" @default.
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