Matches in SemOpenAlex for { <https://semopenalex.org/work/W2896281630> ?p ?o ?g. }
- W2896281630 endingPage "12702" @default.
- W2896281630 startingPage "12695" @default.
- W2896281630 abstract "The catalytic activity of room-temperature ionic liquid 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIM][OTf]) for carbon dioxide (CO2) reduction is reported on a polycrystalline silver electrode as a function of the water content and solution pH. The optimal aqueous dilution was determined to be ca. 10% (v/v), resulting in a reduction of the overpotential required to reduce CO2 in [EMIM][OTf] by 400 mV. The reduction process and products are largely insensitive to pH. CO2 reduction in [EMIM][OTf] with 10% 0.1 M NaHCO3 is achieved with high selectivity for CO with 93.0 ± 4.6% Faradaic efficiency. Hydrogen evolution reaction (HER) is suppressed in the range of neat [EMIM][OTf] (500 ppm water content) to a [EMIM][OTf]/H2O mixture of 10% water content. Conductivity and viscosity of the [EMIM][OTf]/H2O mixture suggest that the ionic liquid ion pair fully dissociates, analogous to dilute KCl solution, where each ion is completely hydrated by water molecules." @default.
- W2896281630 created "2018-10-26" @default.
- W2896281630 creator A5000351870 @default.
- W2896281630 creator A5052294116 @default.
- W2896281630 date "2018-10-19" @default.
- W2896281630 modified "2023-10-13" @default.
- W2896281630 title "Efficient Electrocatalytic Reduction of Carbon Dioxide in 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate and Water Mixtures" @default.
- W2896281630 cites W1492836215 @default.
- W2896281630 cites W1573878304 @default.
- W2896281630 cites W1829643206 @default.
- W2896281630 cites W1936939651 @default.
- W2896281630 cites W1957838521 @default.
- W2896281630 cites W1966781307 @default.
- W2896281630 cites W1985178357 @default.
- W2896281630 cites W1985757919 @default.
- W2896281630 cites W1994204840 @default.
- W2896281630 cites W2000224243 @default.
- W2896281630 cites W2003208951 @default.
- W2896281630 cites W2008686504 @default.
- W2896281630 cites W2008812544 @default.
- W2896281630 cites W2013339174 @default.
- W2896281630 cites W2023496383 @default.
- W2896281630 cites W2023723462 @default.
- W2896281630 cites W2025941325 @default.
- W2896281630 cites W2039639599 @default.
- W2896281630 cites W2041511900 @default.
- W2896281630 cites W2044392760 @default.
- W2896281630 cites W2047249848 @default.
- W2896281630 cites W2051066060 @default.
- W2896281630 cites W2052086659 @default.
- W2896281630 cites W2063031338 @default.
- W2896281630 cites W2076115160 @default.
- W2896281630 cites W2076228841 @default.
- W2896281630 cites W2077965278 @default.
- W2896281630 cites W2080893710 @default.
- W2896281630 cites W2086340877 @default.
- W2896281630 cites W2100681053 @default.
- W2896281630 cites W2114911313 @default.
- W2896281630 cites W2119816877 @default.
- W2896281630 cites W2125470511 @default.
- W2896281630 cites W2144076395 @default.
- W2896281630 cites W2167769924 @default.
- W2896281630 cites W2202057872 @default.
- W2896281630 cites W2293062392 @default.
- W2896281630 cites W2297575632 @default.
- W2896281630 cites W2312329288 @default.
- W2896281630 cites W2313951355 @default.
- W2896281630 cites W2318757145 @default.
- W2896281630 cites W2323906322 @default.
- W2896281630 cites W2332861710 @default.
- W2896281630 cites W2339405166 @default.
- W2896281630 cites W2470317005 @default.
- W2896281630 cites W2474703360 @default.
- W2896281630 cites W2507176469 @default.
- W2896281630 cites W2523021023 @default.
- W2896281630 cites W2532456832 @default.
- W2896281630 cites W2547631353 @default.
- W2896281630 cites W2574347242 @default.
- W2896281630 cites W2583944613 @default.
- W2896281630 cites W2776257250 @default.
- W2896281630 cites W2787734930 @default.
- W2896281630 cites W2916961622 @default.
- W2896281630 doi "https://doi.org/10.1021/acs.energyfuels.8b02750" @default.
- W2896281630 hasPublicationYear "2018" @default.
- W2896281630 type Work @default.
- W2896281630 sameAs 2896281630 @default.
- W2896281630 citedByCount "19" @default.
- W2896281630 countsByYear W28962816302019 @default.
- W2896281630 countsByYear W28962816302020 @default.
- W2896281630 countsByYear W28962816302021 @default.
- W2896281630 countsByYear W28962816302022 @default.
- W2896281630 countsByYear W28962816302023 @default.
- W2896281630 crossrefType "journal-article" @default.
- W2896281630 hasAuthorship W2896281630A5000351870 @default.
- W2896281630 hasAuthorship W2896281630A5052294116 @default.
- W2896281630 hasConcept C118792377 @default.
- W2896281630 hasConcept C147789679 @default.
- W2896281630 hasConcept C154881586 @default.
- W2896281630 hasConcept C161790260 @default.
- W2896281630 hasConcept C17525397 @default.
- W2896281630 hasConcept C178790620 @default.
- W2896281630 hasConcept C179104552 @default.
- W2896281630 hasConcept C184651966 @default.
- W2896281630 hasConcept C185592680 @default.
- W2896281630 hasConcept C186460083 @default.
- W2896281630 hasConcept C21774173 @default.
- W2896281630 hasConcept C52859227 @default.
- W2896281630 hasConceptScore W2896281630C118792377 @default.
- W2896281630 hasConceptScore W2896281630C147789679 @default.
- W2896281630 hasConceptScore W2896281630C154881586 @default.
- W2896281630 hasConceptScore W2896281630C161790260 @default.
- W2896281630 hasConceptScore W2896281630C17525397 @default.
- W2896281630 hasConceptScore W2896281630C178790620 @default.
- W2896281630 hasConceptScore W2896281630C179104552 @default.
- W2896281630 hasConceptScore W2896281630C184651966 @default.
- W2896281630 hasConceptScore W2896281630C185592680 @default.
- W2896281630 hasConceptScore W2896281630C186460083 @default.
- W2896281630 hasConceptScore W2896281630C21774173 @default.